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<journal-id journal-id-type="publisher">global-journal-of-science-frontier-research-b-chemistry</journal-id>
<journal-title-group>
<journal-title>Global Journal of Science Frontier Research - B: Chemistry</journal-title>
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<issn publication-format="print">0975-5896</issn>
<issn publication-format="electronic">2249-4626</issn>
<publisher><publisher-name>Global Journals Publishing Group Incorporated</publisher-name></publisher>
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<article-id pub-id-type="publisher-id">58868</article-id>
<title-group>
<article-title>1.10-Phenanthroline as Anti-Radiation UV Agent: Spectrophotometry Analysis and Modeling</article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author"><name><surname>Rakhman</surname><given-names>Khusna Arif</given-names></name><xref ref-type="aff" rid="aff1" />
</contrib>
<contrib contrib-type="author"><name><surname>Jayali</surname><given-names>Ahmad Muchsin</given-names></name></contrib>
<contrib contrib-type="author"><name><surname>Abdjan</surname><given-names>Muhammad Ikhlas</given-names></name></contrib>
<contrib contrib-type="author"><name><surname>Ahmad</surname><given-names>Andi U.</given-names></name></contrib>
<contrib contrib-type="author"><name><surname>Putra</surname><given-names>Chairil Anjasmara Robo</given-names></name></contrib>
</contrib-group>
<aff id="aff1">INDONESIA, Universitas Khairun</aff>
<pub-date publication-format="electronic" date-type="pub" iso-8601-date="2018-08-31">
<day>31</day>
<month>08</month>
<year>2018</year>
</pub-date>
<volume>18</volume>
<issue>B3</issue>
<fpage>25</fpage>
<lpage>29</lpage>
<abstract><p>Determination of the activity of a 1.10-Phenanthroline compound as an agent of anti UV was measured using a UVVis spectrophotometer. The study of the electronic transition of 1.10-Phenanthroline compounds was carried out computationally with the semi-empirical of ZINDO/s method. The results of determining the potential of the 1.10-Phenanthroline compound as an anti UV radiation agent showed the lowest%Te value of 0.102%, the highest SPF value of 2.328 and the lowest%Tp value of 0.509%. The type of transition found in 3 peaks in the 1.10-Phenanthroline compound shows the transition types; n to π ⃰ and π to π ⃰ . Whereas, molecular orbitals (MO) involved in electron excitation were: 32 (HOMO-1), 33 (HOMO), 34 (LUMO) and 35 (LUMO + 1) with the smallest energy difference value being 33 to 34 excitation of 7.78 eV.</p></abstract>
<kwd-group kwd-group-type="author-generated">
<kwd>the 1.10-phenanthroline</kwd>
<kwd>anti-UV radiation agent</kwd>
<kwd>UV-vis spectrophotometer</kwd>
<kwd>ZINDO/s.</kwd>
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<title>Full Text</title>
<p>Determination of the activity of a 1.10-Phenanthroline compound as an agent of anti UV was measured using a UVVis spectrophotometer. The study of the electronic transition of 1.10-Phenanthroline compounds was carried out computationally with the semi-empirical of ZINDO/s method. The results of determining the potential of the 1.10- Phenanthroline compound as an anti UV radiation agent showed the lowest%Te value of 0.102%, the highest SPF value of 2.328 and the lowest%Tp value of 0.509%. The type of transition found in 3 peaks in the 1.10-Phenanthroline compound shows the transition types; n to Ï€ âƒ° and Ï€ t o Ï€ âƒ°. Whereas, molecular orbitals (MO) involved in electron excitation were: 32 (HOMO-1), 33 (HOMO), 34 (LUMO) and 35 (LUMO + 1) with the smallest energy difference value being 33 to 34 excitation of 7.78 eV.</p>
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