Chemical and Electrochemical Study on the Effectively of Melilotus Officinalis Extract as save Corrosion Inhibitor for Aluminium in 1 M Hydrochloric Acid Solutions

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Chemical and Electrochemical Study on the Effectively of Melilotus Officinalis Extract as save Corrosion Inhibitor for Aluminium in 1 M Hydrochloric Acid Solutions

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Abstract

Melilotus officinalis Extract (MOE), was investigated as a green corrosion inhibitor for aluminium in 1 M HCl solution using weight loss, hydrogen evolution, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. Surface morphology was tested using scanning electron microscope (SEM). The effect of the temperature on corrosion behavior with addition of different concentrations was studied in the temperature range of 25-45 ºC by weight loss method. Polarization curves reveal that the investigated extract is a mixed type inhibitor. The inhibition efficiency was found to increase with increase in the investigated extract concentration and increase with increase in solution temperature. The adsorption of the inhibitor on aluminium surface was found to obey the Temkin’s adsorption isotherm. The activation and adsorption parameters were calculated and discussed. The results obtained from chemical and electrochemical techniques are in good agreement.

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

A.S.Fouda. 2016. "Chemical and Electrochemical Study on the Effectively of Melilotus Officinalis Extract as save Corrosion Inhibitor for Aluminium in 1 M Hydrochloric Acid Solutions". Global Journal of Research in Engineering - C: Chemical Engineering GJRE-C Volume 15 (GJRE Volume 15 Issue C3).

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Journal Specifications

Crossref Journal DOI 10.17406/gjre

Print ISSN 0975-5861

e-ISSN 2249-4596

Keywords
Classification
GJRE-C Classification FOR Code: 290699
Version of record

v1.2

Issue date
January 9, 2016

Language
English
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Chemical and Electrochemical Study on the Effectively of Melilotus Officinalis Extract as save Corrosion Inhibitor for Aluminium in 1 M Hydrochloric Acid Solutions

A.S.Fouda
A.S.Fouda Mansoura University