Effect of Temperature Changes on Critical Micelle Concentration for Tween Series surfactant

dafer mahdy; May Essa Mahmood

Effect of Temperature Changes on Critical Micelle Concentration for Tween Series surfactant

dafer mahdy * §

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May Essa Mahmood

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§ Faculity of Pharmacy / kufa university

Effect of Temperature Changes on Critical Micelle Concentration for Tween Series surfactant

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Abstract

The critical micelle concentration (CMC) for polyoxyethylene sorbitan fatty acid esters (tween) series surfactant was determined by the fluorescence intensity technique. It has been measured against concentration of micelle at temperature range (298-348) °k . at 298°k the CMC for tween (20, 21, 40, 60 and 80) were (0.0499, 0.063, 0.0333, 0.0167 and 0.015) mM respectively. The critical micelle concentration (CMC) for all tween series decreased with increasing carbon atoms number for alkyl group, but increased with increasing the number of oxyethylene group. The CMC for all tween series decreased with increasing temperature, it slightly increased at higher temperature. Thermodynamic parameters (ΔG°m, ΔH°m , ΔS°m) of the micelle formation were calculated from the temperature dependence on the CMC, ΔG°m decreased when increasing temperature above the whole temperature range . It is found that (ΔG°m, ΔH°m, ΔS°m ) decreased with increasing carbon number for alkyl group, but increased with increasing the number of oxyethylene group.

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

dafer mahdy, May Essa Mahmood. 2013. "Effect of Temperature Changes on Critical Micelle Concentration for Tween Series surfactant". Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 13 (GJSFR Volume 13 Issue B4).

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GJSFR Volume 13 Issue B4

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords

CMC micelle Micellization thermodynamic nonionic surfactant Pyrene-3-carboxaldehyde Tween

Classification

GJSFR-B Classification FOR Code: 030602

Submission ReceivedMarch 4, 2013
Peer Review Double Blind
Handling Editor
Accepted March 24, 2013
Published April 5, 2013

Version of record

v1.2

Issue date

May 30, 2013

Language

English

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Article Matrices

Total Score: 146

Country: Iraq

Subject: Global Journal of Science Frontier Research

Authors: May Essa Mahmood, Dhafer A. F. Al-Koofee (PhD/Dr. count: 0)

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