Preparation, Characterisation and Reactions of Stable Adducts of TRIS (Pentafluorophenyl) Antimony (V) Diisothiocyanates.

Ram Nath Prasad Yadav

Preparation, Characterisation and Reactions of Stable Adducts of TRIS (Pentafluorophenyl) Antimony (V) Diisothiocyanates.

Ram Nath Prasad Yadav * §

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§ Tribhuvan University

Preparation, Characterisation and Reactions of Stable Adducts of TRIS (Pentafluorophenyl) Antimony (V) Diisothiocyanates.

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Abstract

A series of new stable adducts of tris (pentafluo-rophenyl)antimony(V) diisothiocyante of the type (C 6 H 5 ) 3 Sb(NCS) 2 .L. Where, L = dipropyl formamide (DPF), 3-methylpyridine(3-Picoline), dimethyl formamide (DMF), tryphenylphosphine oxide(Ph 3 PO), triphenylarsine oxide (Ph 3 AsO), dimethyl sulfoxide (DMSO), thiourea (TU), pyridine(C 5 H 5 N) have been synthesized by the reaction of tris (pentafluorophenyl)antimony(V) diisothiocyanate with desired ligand in anhydrous methanol. Tris(pentafluorophenyl) antimony diisothiocyanate was obtained by the metathetical reaction of tris(pentafluorophenyl) antimony (V) dichloride and potassium thiocyanate in anhydrous methanol. The molecular weight measurement and molar conductance data of the complexes revealed them to be monomeric and non-conducting in nature. Elemental analysis and IR data indicates that the complexes have hexacoordinated octahedral structure.

References

16 Cites in Article

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1. Sumee Kumar,Shashikan Pandey,Rajendra Prasad (1990). Some properties of pseudo-slant submanifolds of a Sasakian manifold. SERIES III - MATEMATICS, INFORMATICS, PHYSICS, 61(12)(2), 365-380.
2. M Hall,D Sowerby (1988). Phenylchloroantimo (III) nates; their preparations and the crystal structure of Me 4 N. PhSbCl, 3
3. Michael Hall,D Sowerby (1983). Donor properties of triphenylantimony dihalides : preparation and crystal structures of Ph₃SbCl₂·SbCl₃and [Ph₃SbCl][SbCl₆]. J. Chem. Soc., Dalton Trans., 347(6), 1095-1099.
4. H Meinema,J Noltes,Francesca Di Bianca,N Bertazzi,Eleonora Rivarola,R Barbieri (1976). Investigations on organoantimony compounds. Journal of Organometallic Chemistry, 107(2), 249-255.
5. Michael Nunn,Michael J. Begley,D Bryan Sowerby,Ionel Haiduc (1996). Complexes of organoantimony(III) and (V) halides with nitrogen donors. Polyhedron, 15(19), 3167-3174.
6. Mishra Premraj,N (1991). Preparation and characterization of molecular adduct of diarylantimony(V) chloride, R 2 SbCl 3. L. Ind. J. Chem, 30, 901-903.
7. Premraj,A Agarwal,A Saxena (1989). The preparation of pentafluorophenyl antimony(III) and antimony(V) halides and mixed halides. J. Fluorine Chem, 42, 163-172.
8. Premraj,A Saxena,K Singhal,A Ranjan (1985). Synthesis and some reactions of tris(pentafluorophenyl)antimony compounds. Polyh-e dron, 4, 251-258.
9. K Singhal,R Yadav,Premraj,A Agarwal (2002). On the Lewis acidity of tris(pentafluorophenyl)antimony(V) dichloride towards neutral monodentate O, N and S donor ligands. J. Fluorine Chem, 121, 131-134.
10. A Vogel (1971). Practical Organic Chemistry. Practical Organic Chemistry
11. R Yadav (2012). Synthesis and Characterization of Anionic Lanthanide(III) Complexes with a Bidentate Sulfonylamidophosphate (SAPh) Ligand. Nep. J. of Integrated Sciences, 2(1), 14-19.
12. R Yadav (2012). Metals in oncology: An overview. Academic Voices, 2(1), 54-58.
13. R Yadav (2013). Synthesis, characterization and reactions of cationic complexes of arylantimony(III) chlorides ArnSbCl 3-n with perchlorate and tetrafluoroborate anions. Int. J. Appl. Sci. Biotechnol, 1(2), 42-48.
14. R Yadav (2013). Preparation and characterization of complex bis(pentafluorophenyl)antimony(V) anions of the type [(R f ) 2 SbCl 3 X] ͞. Int. J. Appl. Sci. Biotecnol, 1(3), 90-96.
15. Ram Yadav (2013). Insecticidal and Antimicrobial Activity of Triaryl Antimony(V) Derivatives. Academic Voices: A Multidisciplinary Journal, 3(1), 40-45.
16. R Yadav (2014). Synthesis and characterization of 1-(4-methylthiazol-2-yl)-3-propyl thiourea. International Journal of Advanced Research in Biological Sciences (IJARBS), 4(7), 53-57.

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

Ram Nath Prasad Yadav. 2014. "Preparation, Characterisation and Reactions of Stable Adducts of TRIS (Pentafluorophenyl) Antimony (V) Diisothiocyanates.". Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 14 (GJSFR Volume 14 Issue B3).

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GJSFR Volume 14 Issue B3

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords

diisothiocyanate elemental analysis hexacoordinate IR spectra octahedral stable adduct tris(pentafluorophenyl) antimony

Classification

GJSFR-B Classification FOR Code: 039999

Submission ReceivedApril 17, 2014
Peer Review Double Blind
Handling Editor
Accepted May 16, 2014
Published June 21, 2014

Version of record

v1.2

Issue date

June 21, 2014

Language

English

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Total Score: 101

Country: Nepal

Subject: Global Journal of Science Frontier Research - B: Chemistry

Authors: Ram Nath Prasad Yadav (PhD/Dr. count: 0)

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