Triarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions

Triarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions

Ram Nath Prasad Yadav

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Tribhuvan University

Triarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions

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Abstract

A series of new triarylantimony(V) dicarboxylates of the general formula Ar 3 SbL 2 (where Ar = C 6 H 5 and L = C 6 H 5 CONHCH 2 COO -, C 6 H 2 (OH) 3 COO -, C 6 H 5 COO -, C 6 H 5 C 2 H 2 COO -, C 6 H 4 (OH)COO -, (C 6 H 5 ) 2 (OH)C.COO -) have been prepared by the reaction of triarylantimony(V) dichloride and a carboxylic acid in the presence of triethylamine as well as the metathesis of sodium or silver salt of the carboxylic acid andtriarylantimony(V) dichloride. The newly synthesized compounds have been characterized by conventional methods. A tentative trigonalbipyramidal structure is suggested in which (OCOR) group occupy axial position and the three organic groups are situated at the equatorial position. The melting points of compounds did not change even after prolong stirring with water at room temperature for several hours indicating their hydrolytic stability.

References

17 Cites in Article

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Ming‐may Chang,Kai Su,Jeremy Musher (1974). Some New Organoantimony(V) Compounds.
G Doak,G Long,L Freedman (1965). The Infrared spectra of some phenyl substituted pentavalent antimony compounds.
G Doak,G Long,L Freedman (1974). Antimony: Annual survey covering the year 1975.
R Goel,D Ridley (1972). Studies on trimethyl and triphenylantimony(V) derivatives of haloacetic acids.
J Hevyanek,J Mleziva,L Lycka (1978). Triphenylantimonydiester preparation.
H Meinema,J Noltes (1972). Investigations on organoantimonycompounds:VI. Preparation and properties of thermally stable dialkylantimony(V) compounds of the types R 2 Sb(OR) 3 , R 2 Sb(OAc) 3 and R 2 Sb(O)OH.
Ranjan Premraj,K Singhal,R Rastogi (1984). Synthesis and characterization of tetraarylstibonium amides, oximates and carboxylates.
K Singhal,R Rastogi,Premraj (1987). Synthesis and biological evaluation of some substituted tetriaryarylantimony(V) derivatives.
K Swamy,Said Kumara,A Musa,M Netaji (1999). A heptacoordinate mononuclear diphenylantimonycarboylate.
A Vogel (1989). Practical Organic Chemistry.
R Yadav (2014). The Investigation of Synthesis, Spectroscopic and Thermal Characterization of Cu(II) Complexes of Some Tridentate Ligands.
R Yadav (2014). Preparation, characterization and reactions of stable adducts of tris(pentaflurophenyl) antimony (V) diisothiocyanates.
Ram Yadav (2013). Synthesis, characterisation and reactions of cationic complexes of Arylantimony (III) chlorides ArnSbCl3-n with perchlorate and tetrafluoroborate anions.
R Yadav (2013). Insecticidal and antimicrobial activity of triarylantimony(V) derivatives.
R Yadav (2012). Synthesis and Characterization of Anionic Lanthanide(III) Complexes with a Bidentate Sulfonylamidophosphate (SAPh) Ligand.
R Yadav (2012). Metals in oncology: An overview.
Weiwei Qin,Shuji Yasuike,Naoki Kakusawa,Jyoji Kurita (2008). ChemInform Abstract: Palladium‐Catalyzed Carbonylative Cross‐Coupling Reaction of Triarylantimony Dicarboxylates with Arylboronic Acids: Synthesis of Biaryl Ketones..

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

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No ethics committee approval was required for this article type.

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Not applicable for this article.

How to Cite This Article

Ram Nath Prasad Yadav. 2015. \u201cTriarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 15 (GJSFR Volume 15 Issue B3).

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GJSFR Volume 15 Issue B3

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

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GJSFR-B Classification FOR Code: 259999

Submission ReceivedApril 29, 2015
Peer Review Double Blind
Handling Editor
Accepted May 25, 2015
Published June 5, 2015

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v1.2

Issue date

June 11, 2015

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Article Matrices

Total Score: 101

Country: Nepal

Subject: Global Journal of Science Frontier Research - B: Chemistry

Authors: Ram Nath Prasad Yadav (PhD/Dr. count: 0)

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Total Views: 4296

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