FTIR and Optical Absorption Studies Of New Magnesium Lead Borate Glasses

Article ID

SFR6P8N1

FTIR and Optical Absorption Studies Of New Magnesium Lead Borate Glasses

Dr. G. Ramadevudu
Dr. G. Ramadevudu Osmania University, Hyderabad, India.
S.Lakshmi Srinivasa Rao
S.Lakshmi Srinivasa Rao
Md. Shareeffuddin
Md. Shareeffuddin
M.Narasimha Chary
M.Narasimha Chary
M.Lakshmipathi Rao
M.Lakshmipathi Rao
DOI

Abstract

New magnesium lead borate glasses (10-x) MgO-xMgCl2-40PbO-50B2O3 (x = 0, 1, 2, 3, 4, 5, 6, 7, 8, and 10 mole%) were prepared by melt quenching technique. Fourier transform infrared spectroscopic studies revealed the presence of BO3 trigonal and BO4 tetrahedral structural units in these glasses. The optical energy band gaps, Urbach energies and theoretical refractive index values are reported. No considerable structural changes with the composition are observed. FTIR revealed the formation of NBOs and the behaviour of MgO as glass network modifier. The expansion of B-O network with increasing x mole% is attributed to the presence of Chlorine ions.

FTIR and Optical Absorption Studies Of New Magnesium Lead Borate Glasses

New magnesium lead borate glasses (10-x) MgO-xMgCl2-40PbO-50B2O3 (x = 0, 1, 2, 3, 4, 5, 6, 7, 8, and 10 mole%) were prepared by melt quenching technique. Fourier transform infrared spectroscopic studies revealed the presence of BO3 trigonal and BO4 tetrahedral structural units in these glasses. The optical energy band gaps, Urbach energies and theoretical refractive index values are reported. No considerable structural changes with the composition are observed. FTIR revealed the formation of NBOs and the behaviour of MgO as glass network modifier. The expansion of B-O network with increasing x mole% is attributed to the presence of Chlorine ions.

Dr. G. Ramadevudu
Dr. G. Ramadevudu Osmania University, Hyderabad, India.
S.Lakshmi Srinivasa Rao
S.Lakshmi Srinivasa Rao
Md. Shareeffuddin
Md. Shareeffuddin
M.Narasimha Chary
M.Narasimha Chary
M.Lakshmipathi Rao
M.Lakshmipathi Rao

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Dr. G. Ramadevudu. 2012. “. Global Journal of Science Frontier Research – A: Physics & Space Science GJSFR-A Volume 12 (GJSFR Volume 12 Issue A4): .

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Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

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GJSFR Volume 12 Issue A4
Pg. 41- 46
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FTIR and Optical Absorption Studies Of New Magnesium Lead Borate Glasses

Dr. G. Ramadevudu
Dr. G. Ramadevudu Osmania University, Hyderabad, India.
S.Lakshmi Srinivasa Rao
S.Lakshmi Srinivasa Rao
Md. Shareeffuddin
Md. Shareeffuddin
M.Narasimha Chary
M.Narasimha Chary
M.Lakshmipathi Rao
M.Lakshmipathi Rao

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