1.10-Phenanthroline as Anti-Radiation UV Agent: Spectrophotometry Analysis and Modeling

1
Khusna Arif Rakhman
Khusna Arif Rakhman
2
Ahmad Muchsin Jayali
Ahmad Muchsin Jayali
3
Muhammad Ikhlas Abdjan
Muhammad Ikhlas Abdjan
4
Andi U. Ahmad
Andi U. Ahmad
5
Chairil  Anjasmara Robo Putra
Chairil Anjasmara Robo Putra
1 Universitas Khairun

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Determination of the activity of a 1.10-Phenanthroline compound as an agent of anti UV was measured using a UVVis spectrophotometer. The study of the electronic transition of 1.10-Phenanthroline compounds was carried out computationally with the semi-empirical of ZINDO/s method. The results of determining the potential of the 1.10-Phenanthroline compound as an anti UV radiation agent showed the lowest%Te value of 0.102%, the highest SPF value of 2.328 and the lowest%Tp value of 0.509%. The type of transition found in 3 peaks in the 1.10-Phenanthroline compound shows the transition types; n to π ⃰ and π to π ⃰ . Whereas, molecular orbitals (MO) involved in electron excitation were: 32 (HOMO-1), 33 (HOMO), 34 (LUMO) and 35 (LUMO + 1) with the smallest energy difference value being 33 to 34 excitation of 7.78 eV.

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

Khusna Arif Rakhman. 2018. \u201c1.10-Phenanthroline as Anti-Radiation UV Agent: Spectrophotometry Analysis and Modeling\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 18 (GJSFR Volume 18 Issue B3): .

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GJSFR Volume 18 Issue B3
Pg. 25- 29
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Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

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September 5, 2018

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Determination of the activity of a 1.10-Phenanthroline compound as an agent of anti UV was measured using a UVVis spectrophotometer. The study of the electronic transition of 1.10-Phenanthroline compounds was carried out computationally with the semi-empirical of ZINDO/s method. The results of determining the potential of the 1.10-Phenanthroline compound as an anti UV radiation agent showed the lowest%Te value of 0.102%, the highest SPF value of 2.328 and the lowest%Tp value of 0.509%. The type of transition found in 3 peaks in the 1.10-Phenanthroline compound shows the transition types; n to π ⃰ and π to π ⃰ . Whereas, molecular orbitals (MO) involved in electron excitation were: 32 (HOMO-1), 33 (HOMO), 34 (LUMO) and 35 (LUMO + 1) with the smallest energy difference value being 33 to 34 excitation of 7.78 eV.

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1.10-Phenanthroline as Anti-Radiation UV Agent: Spectrophotometry Analysis and Modeling

Khusna Arif Rakhman
Khusna Arif Rakhman Universitas Khairun
Ahmad Muchsin Jayali
Ahmad Muchsin Jayali
Muhammad Ikhlas Abdjan
Muhammad Ikhlas Abdjan
Andi U. Ahmad
Andi U. Ahmad
Chairil  Anjasmara Robo Putra
Chairil Anjasmara Robo Putra

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