1.10-Phenanthroline as Anti-Radiation UV Agent: Spectrophotometry Analysis and Modeling

Khusna Arif Rakhman; Ahmad Jayali; Muhammad Abdjan; Andi Ahmad; Chairil Putra

1.10-Phenanthroline as Anti-Radiation UV Agent: Spectrophotometry Analysis and Modeling

Khusna Arif Rakhman * §

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Ahmad Muchsin Jayali

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Muhammad Ikhlas Abdjan

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Andi U. Ahmad

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Chairil Anjasmara Robo Putra

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§ Universitas Khairun

1.10-Phenanthroline as Anti-Radiation UV Agent: Spectrophotometry Analysis and Modeling

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Abstract

Determination of the activity of a 1.10-Phenanthroline compound as an agent of anti UV was measured using a UVVis spectrophotometer. The study of the electronic transition of 1.10-Phenanthroline compounds was carried out computationally with the semi-empirical of ZINDO/s method. The results of determining the potential of the 1.10-Phenanthroline compound as an anti UV radiation agent showed the lowest%Te value of 0.102%, the highest SPF value of 2.328 and the lowest%Tp value of 0.509%. The type of transition found in 3 peaks in the 1.10-Phenanthroline compound shows the transition types; n to π ⃰ and π to π ⃰ . Whereas, molecular orbitals (MO) involved in electron excitation were: 32 (HOMO-1), 33 (HOMO), 34 (LUMO) and 35 (LUMO + 1) with the smallest energy difference value being 33 to 34 excitation of 7.78 eV.

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No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

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How to Cite This Article

Khusna Arif Rakhman, Ahmad Muchsin Jayali, Muhammad Ikhlas Abdjan, Andi U. Ahmad, Chairil Anjasmara Robo Putra. 2018. "1.10-Phenanthroline as Anti-Radiation UV Agent: Spectrophotometry Analysis and Modeling". Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 18 (GJSFR Volume 18 Issue B3).

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GJSFR Volume 18 Issue B3

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

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GJSFR-B Classification FOR Code: 030199

Submission ReceivedJuly 18, 2018
Peer Review Double Blind
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Accepted August 17, 2018
Published August 31, 2018

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Issue date

September 5, 2018

Language

English

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Article Matrices

Total Score: 105

Country: Indonesia

Subject: Global Journal of Science Frontier Research - B: Chemistry

Authors: Khusna Arif Rakhman, Ahmad Muchsin Jayali, Muhammad Ikhlas Abdjan, Andi U. Ahmad, Chairil Anjasmara Robo Putra (PhD/Dr. count: 0)

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