1-Octanol/Water Partition Coefficients of Dialkylated Methylimidazolium Halide Salts

John H. Summerfield; Marissa K. Gard; Elliot G. Ennis

1-Octanol/Water Partition Coefficients of Dialkylated Methylimidazolium Halide Salts

John H. Summerfield * §

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Marissa K. Gard

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Elliot G. Ennis

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§ Missouri Southern State University

1-Octanol/Water Partition Coefficients of Dialkylated Methylimidazolium Halide Salts

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Abstract

Dialkylated methylimidazolium halide salts are a current research topic. The 1octanol/water partition coeffcient for these salts has come to signify the tendency of a charged organic molecule to cross a biological membrane, be sequested in soil, and indicate the lethal dose of the chemical. The purpose of this work is to add to existing data for the 1-octanol/water partition coeffcient for these salts. The novelty of this work is that dialkylated methylimidazolium salts are investigated.

References

35 Cites in Article

Reference Format

L Ropel,L Belvèze,S Aki (2005). 1-octanol-water Partition Coefficients of Imidazolium-based Ionic Liquids.
F Hernat,H Yu (2015). Ion Chromatography of Tri-Substituted Imidazolium Ionic Liquid Cations: Method and Application for Octanol-Water Partition Coefficient (K OW ) Determination.
Victor Levin (1980). Relationship of octanol/water partition coefficient and molecular weight to rat brain capillary permeability.
Chul-Woong Cho,Ulrich Preiss,Christian Jungnickel,Stefan Stolte,Jürgen Arning,Johannes Ranke,Andreas Klamt,Ingo Krossing,Jorg Thöming (2011). Ionic Liquids: Predictions of Physicochemical Properties with Experimental and/or DFT-Calculated LFER Parameters To Understand Molecular Interactions in Solution.
Urszula Domańska,Marek Królikowski,Aneta Pobudkowska,Patrycja Bocheńska (2012). Solubility of ionic liquids in water and octan-1-ol and octan-1-ol/water, or 2-phenylethanol/water partition coefficients.
E Ennis,S Handy (2009). A Facile Route to C2-Substituted Imidazolium Ionic Liquids.
Till Cremer,Claudia Kolbeck,Kevin Lovelock,Natalia Paape,René Wölfel,Peter Schulz,Peter Wasserscheid,Henry Weber,Jens Thar,Barbara Kirchner,Florian Maier,Hans‐peter Steinrück (2010). Towards a Molecular Understanding of Cation–Anion Interactions—Probing the Electronic Structure of Imidazolium Ionic Liquids by NMR Spectroscopy, X‐ray Photoelectron Spectroscopy and Theoretical Calculations.
Walid Awad,Jeffrey Gilman,Marc Nyden,Richard Harris,Thomas Sutto,John Callahan,Paul Trulove,Hugh Delong,Douglas Fox (2004). Thermal degradation studies of alkyl-imidazolium salts and their application in nanocomposites.
Scott Handy,Maurice Okello (2005). The 2-Position of Imidazolium Ionic Liquids: Substitution and Exchange.
T Endo,K Nishikawa Effects of Methylation at Position 2 of Cation Ring on Rotational Dynamics of Imidazolium-Based Ionic Liquids Investigated by NMR Spectroscopy.
Takatsugu Endo,Tatsuya Kato,Keiko Nishikawa (2010). Effects of Methylation at the 2 Position of the Cation Ring on Phase Behaviors and Conformational Structures of Imidazolium-Based Ionic Liquids.
Q Lin,F Huang,M Liu (2008). Imidazolium-Salt-Based Fluorescent Chemosensor for Cu(II), Zn(II) and Co(II).
P Sassi,M Paolantoni,R Cataliotti (2004). Water/Alcohol Mixtures: A Spectroscopic Study of the Water-saturated 1-octanol Solution.
Jack De Bruijn,Frans Busser,Willem Seinen,Joop Hermens (2009). Determination of octanol/water partition coefficients for hydrophobic organic chemicals with the “slow-stirring” method.
G Veith,N Austin,R Morris (1979). A rapid method for estimating log P for organic chemicals.
Robert Rapaport,Steven Eisenreich (1984). Chromatographic determination of octanol-water partition coefficients (Kow's) for 58 PCB polychlorinated biphenyl congeners.
Us Epa (1996). Product Properties Test Guidelines: Partition Coefficients (n-1-octanol/water), Estimation by Liquid Chromatography.
H Devoe,M Miller,S Wasik (1981). Generator Columns and High Pressure Liquid Chromatography for Determining Aqueous Solubilities and Octanol-Water Partition Coefficients of Hydrophobic Substances.
Mark Harris,Jennifer Logan (2014). Determination of log <i>K</i><sub>ow</sub> Values for Four Drugs.
(2015). Masthead.
Tiejun Cheng,Yuan Zhao,Xun Li,Fu Lin,Yong Xu,Xinglong Zhang,Yan Li,Renxiao Wang,Luhua Lai (2007). Computation of Octanol−Water Partition Coefficients by Guiding an Additive Model with Knowledge.
D Evans,S Rubenstein (2015). ChemDraw Professional.
Van Leeuwen (2003). Technical Guidance Document on Risk Assessment, European Communities.
(2015). Sussex Drug Discovery Centre, sussexdrug discovery.
M Montalbán,M Collado-González,R Trigo (2015). Experimental Measurements of Octanol-Water Partition Coefficients of Ionic Liquids.
Dan Hâncu,Eric Beckman (2001). Generation of hydrogen peroxide directly from H2 and O2 using CO2 as the solvent.
C Margulis,H Stern,B Berne (2002). Computer Simulation of a Green Chemistry Room-temperature Ionic Solvent.
Alexandre Chapeaux,Luke Simoni,Mark Stadtherr,Joan Brennecke (2007). Liquid Phase Behavior of Ionic Liquids with Water and 1-Octanol and Modeling of 1-Octanol/Water Partition Coefficients.
S Katkevica,A Zicmanis,P Mekss (2010). Imidazolium and Pyridinium Salts---Solvents Influencing the Rate and Direction of the Fries, Beckmann, and Claisen Rearrangements.
Ana Cláudio,Mara Freire,Carmen Freire,Armando Silvestre,João Coutinho (2010). Extraction of vanillin using ionic-liquid-based aqueous two-phase systems.
Mara Freire,Catarina Neves,Isabel Marrucho,José Canongia Lopes,Luís Rebelo,João Coutinho (2010). High-performance extraction of alkaloids using aqueous two-phase systems with ionic liquids.
Yun Deng,Pascale Besse-Hoggan,Martine Sancelme,Anne-Marie Delort,Pascale Husson,Margarida Costa Gomes (2011). Influence of oxygen functionalities on the environmental impact of imidazolium based ionic liquids.
D Mackay,A Bobra,W Shiu,S Yalkowsky (1980). Relationships between aqueous solubility and octanol-water partition coefficients.
S Banerjee,S Yalkowsky,S Valvani (1980). Water Solubility and Octanol/water Partition Coefficients of Organics. Limitations of the Solubility-partition Coefficient Correlation.
D Hartmann,K Shimizu,F Siopa (2015). Plasma Membrane Permeability by Ionic Liquids: A matter of Charge.

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

John Summerfield, Marissa Gard, Elliot Ennis. 2016. "1-Octanol/Water Partition Coefficients of Dialkylated Methylimidazolium Halide Salts". Global Journal of Science Frontier Research, Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 15 (GJSFR Volume 15 Issue B6).

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GJSFR Volume 15 Issue B6

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords

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Classification

GJSFR-B Classification FOR Code: 860602

Submission ReceivedOctober 31, 2015
Peer Review Double Blind
Handling Editor
Accepted November 28, 2015
Published December 13, 2015

Version of record

v1.2

Issue date

January 17, 2016

Language

English

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Article Matrices

Total Score: 177

Country: United States

Subject: Global Journal of Science Frontier Research

Authors: Marissa K. Gard, Elliot G. Ennis, John H. Summerfield (PhD/Dr. count: 0)

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