Neural Networks and Rules-based Systems used to Find Rational and Scientific Correlations between being Here and Now with Afterlife Conditions
Neural Networks and Rules-based Systems used to Find Rational and
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A new trend in extraction and preconcentration of chromium (VI) using laboratory-made azo dye reagent 2-[benzenethiazolylazo]-4-benzenenaphthol (BTABN) after cloud-point extraction (CPE) and its determination by spectrophotometrically. The method involved the reaction of Cr 2 O 7 2-with BTABN in acidic medium forming a hydrophobic ion-association complex [HBTABN][HCr 2 O 7 ] which is entrapped into micelle-mediating solvent (Triton X-100) and the Cr(VI) detected spectrophotometrically at λ max of 475 nm. The effect of the several factors on the CPE efficiency is optimized by one-factor-at-a-time (OFAT). Extensive thermodynamic study has been presented to understand the mechanism of extraction and solubilisation of ion-association complex in micelles. The interferences effect of divers ions is also considered. Under the optimized conditions, enrichment factor of 270 is achieved leading to limit of detection and limit of quantitation of 0.017 and 0.0568 μg mL -1 respectively. The linearity of 0.1-2.0 μg mL – 1 and sensitivity in term of molar absorptivity is 4.47×104 L.mol -1 .cm -1 are obtained .The precision (RSD%; n=7) of the proposed method is of 0.31% % at 2.0 μg Cr (VI) mL -1 . This method is applied in the determination of Cr (VI) in various environmental and botanical samples.
Zuhair A-A Khammas. 2014. \u201cA New Spectrophotometric Determination of Chromium (VI) As Cr2O72- After Cloud-Point Extraction using a Laboratory-Made Organic Reagent\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 13 (GJSFR Volume 13 Issue B8): .
Crossref Journal DOI 10.17406/GJSFR
Print ISSN 0975-5896
e-ISSN 2249-4626
The methods for personal identification and authentication are no exception.
Total Score: 103
Country: Iraq
Subject: Global Journal of Science Frontier Research - B: Chemistry
Authors: Zuhair A-A Khammas, Shawkat K. Jawad, Ibtehage R. Ali (PhD/Dr. count: 0)
View Count (all-time): 149
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Publish Date: 2014 01, Mon
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A new trend in extraction and preconcentration of chromium (VI) using laboratory-made azo dye reagent 2-[benzenethiazolylazo]-4-benzenenaphthol (BTABN) after cloud-point extraction (CPE) and its determination by spectrophotometrically. The method involved the reaction of Cr 2 O 7 2-with BTABN in acidic medium forming a hydrophobic ion-association complex [HBTABN][HCr 2 O 7 ] which is entrapped into micelle-mediating solvent (Triton X-100) and the Cr(VI) detected spectrophotometrically at λ max of 475 nm. The effect of the several factors on the CPE efficiency is optimized by one-factor-at-a-time (OFAT). Extensive thermodynamic study has been presented to understand the mechanism of extraction and solubilisation of ion-association complex in micelles. The interferences effect of divers ions is also considered. Under the optimized conditions, enrichment factor of 270 is achieved leading to limit of detection and limit of quantitation of 0.017 and 0.0568 μg mL -1 respectively. The linearity of 0.1-2.0 μg mL – 1 and sensitivity in term of molar absorptivity is 4.47×104 L.mol -1 .cm -1 are obtained .The precision (RSD%; n=7) of the proposed method is of 0.31% % at 2.0 μg Cr (VI) mL -1 . This method is applied in the determination of Cr (VI) in various environmental and botanical samples.
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