A New Spectrophotometric Determination of Chromium (VI) As Cr2O72- After Cloud-Point Extraction using a Laboratory-Made Organic Reagent

A New Spectrophotometric Determination of Chromium (VI) As Cr2O72- After Cloud-Point Extraction using a Laboratory-Made Organic Reagent

Zuhair A-A Khammas

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Shawkat K. Jawad

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Ibtehage R. Ali

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University of Baghdad

A New Spectrophotometric Determination of Chromium (VI) As Cr2O72- After Cloud-Point Extraction using a Laboratory-Made Organic Reagent

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Abstract

A new trend in extraction and preconcentration of chromium (VI) using laboratory-made azo dye reagent 2-[benzenethiazolylazo]-4-benzenenaphthol (BTABN) after cloud-point extraction (CPE) and its determination by spectrophotometrically. The method involved the reaction of Cr 2 O 7 2-with BTABN in acidic medium forming a hydrophobic ion-association complex [HBTABN][HCr 2 O 7 ] which is entrapped into micelle-mediating solvent (Triton X-100) and the Cr(VI) detected spectrophotometrically at λ max of 475 nm. The effect of the several factors on the CPE efficiency is optimized by one-factor-at-a-time (OFAT). Extensive thermodynamic study has been presented to understand the mechanism of extraction and solubilisation of ion-association complex in micelles. The interferences effect of divers ions is also considered. Under the optimized conditions, enrichment factor of 270 is achieved leading to limit of detection and limit of quantitation of 0.017 and 0.0568 μg mL -1 respectively. The linearity of 0.1-2.0 μg mL – 1 and sensitivity in term of molar absorptivity is 4.47×104 L.mol -1 .cm -1 are obtained .The precision (RSD%; n=7) of the proposed method is of 0.31% % at 2.0 μg Cr (VI) mL -1 . This method is applied in the determination of Cr (VI) in various environmental and botanical samples.

References

23 Cites in Article

Reference Format

M Prasad (2008). Trace Elements as Contaminants and Nutrients.
(1998). World Health Organization: Guidelines for Drinking Water Quality.
Epa (2005). The drinking water criteria document on Chromium.
N Srivastava,M Jha,I Mall,D Singh (2010). Application of genetic engineering for chromium removal from industrial wastewater.
A Mizuike (2010). Enrichment techniques for inorganic trace analysis.
Shayesteh Dadfarnia,Ali Shabani,Ellahe Kamranzadeh (2010). Selective cloud point extraction and preconcentration of trace amounts of cadmium prior to flame atomic absorption spectrometric determination.
C Katsaounos,Z Giokas,D Vlessidis,A Paleologos,E Karayannis,M (2003). The use of surfactant-based separation techniques for monitoring of orthophosphate in natural waters and wastewater.
Z Khammas,A-A Ali,S Jawad (2012). Cloud point extraction and micro amount determination of cadmium as chloro anion complex in realsSamples by using molecular spectrophotometry.
Z Khammas,A-A Jawad,A Ali,I (2013). A New Approach for Extraction and Determination of Manganese in Environmental Samples Using Cloud-Point Extraction Coupled with Spectrophotometry.
M Langová-Hniličková,L Sommer (1969). Reaction of gallium and indium with 4-(2-Thiazolylazo) resorcinol.
Zeynep Yıldız,Gulsin Arslan,Ali Tor (1995). Preconcentrative separation of chromium(III) species from chromium(VI) by cloud point extraction and determination by flame atomic absorption spectrometry.
N F Al-Mutawali (2000). Extraction of Mo (VI) ,W (VI) by use crown ether DB18C6.
M Purkait,S Dasgupta,S De (2009). Determination of thermodynamic parameters for the cloud point extraction of different dyes using TX-100 and TX-114.
Willie Hinze,Edmondo Pramauro (1993). A Critical Review of Surfactant-Mediated Phase Separations (Cloud-Point Extractions): Theory and Applications.
V Doroschuk,S Lelyushok,V Ishchenko,S Kulichenko (2004). Flame atomic absorption determination of manganese(II) in natural water after cloud point extraction.
L Madhuchandr,N Nanda,K Jayaveera (2011). Determination of chromium in different water samples using cloud point extraction (CPE) coupled with flame atomic absorption spectrometry (FAAS).
K Suvardhan,R Lekkala,K Janardhanam (2008). Speciation determination of chromium (III) and (VI) using preconcentration cloud point extraction with flame atomic absorption spectrometry (FAAS).
Y Li,B Hu,Z Jiang,T Wu Speciation of chromium in water samples by cloud point extraction combined with low temperature electrothermal vaporization ICP-OES.
Farzaneh Shemirani,Shiva Abkenar,Aazam Mirroshandel,Masood Niasari,Reyhaneh Kozania (2003). Preconcentration and Speciation of Chromium in Water Samples by Atomic Absorption Spectrometry after Cloud-Point Extraction.
(2011). Multiple Sclerosis: Perspectives in Treatment and Pathogenesis.
D Longpré (1999). Health Canada perspective: the role of geochemical data in CCME soil quality guidelines and human health risk assessment.
O O.P. Bansal (2011). Heavy Metals in Soils of Aligarh District: Depth wise Distribution and Accumulation of Cd, Cr, Ni and Pb in Vegetable Crops.
S Dudka (1992). Evaluation of total content of macro-and microelements in the surface layer of soil in Poland.

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

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Not applicable for this article.

How to Cite This Article

Zuhair A-A Khammas. 2014. \u201cA New Spectrophotometric Determination of Chromium (VI) As Cr2O72- After Cloud-Point Extraction using a Laboratory-Made Organic Reagent\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 13 (GJSFR Volume 13 Issue B8).

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GJSFR Volume 13 Issue B8

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords

chromium oxyanion ion-association complex cloud-point extraction new azo dye reagent Spectrophotometry

Submission ReceivedOctober 27, 2013
Peer Review Double Blind
Handling Editor
Accepted November 19, 2013
Published December 4, 2013

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January 20, 2014

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Article Matrices

Total Score: 103

Country: Iraq

Subject: Global Journal of Science Frontier Research - B: Chemistry

Authors: Zuhair A-A Khammas, Shawkat K. Jawad, Ibtehage R. Ali (PhD/Dr. count: 0)

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