Adsorption Kinetics and Mass Balance Mathematical Model of Monoethanolamine Surface-Modified Palm Shell Activated Carbon for Carbon Dioxide Dynamic Adsorption in Fixed Bed Column

Adsorption Kinetics and Mass Balance Mathematical Model of Monoethanolamine Surface-Modified Palm Shell Activated Carbon for Carbon Dioxide Dynamic Adsorption in Fixed Bed Column

Saad Hashim Khalil

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National University of Singapore

Adsorption Kinetics and Mass Balance Mathematical Model of Monoethanolamine Surface-Modified Palm Shell Activated Carbon for Carbon Dioxide Dynamic Adsorption in Fixed Bed Column

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Abstract

Dynamic adsorption kinetics results indicated that monoethanolamine-carbon dioxide (MEA-CO 2 ) reaction in fixed bed column packed with MEA-impregnated activated carbon (AC) particles is pseudo first order reaction. The controlling step (slow step) of adsorption is the mass transfer of CO 2 molecules form the feed gas bulk stream to the surface of the adsorbent through the boundary layer (external diffusion). A Dubinin-Astakhov and Avrami models showed that adsorption of CO 2 on MEA-impregnated activated carbon particles is homogeneous. The suggested mass balance model exhibited good agreement with the experimental results for both MEA-impregnated and non-impregnated AC, which they show also that there is no difference in adsorption rates between the two adsorption beds.

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No external funding was declared for this work.

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The authors declare no conflict of interest.

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How to Cite This Article

Saad Hashim Khalil. 2026. \u201cAdsorption Kinetics and Mass Balance Mathematical Model of Monoethanolamine Surface-Modified Palm Shell Activated Carbon for Carbon Dioxide Dynamic Adsorption in Fixed Bed Column\u201d. Global Journal of Research in Engineering - C: Chemical Engineering GJRE-C Volume 23 (GJRE Volume 23 Issue C1): .

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GJRE Volume 23 Issue C1
Pg. 11- 19

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Crossref Journal DOI 10.17406/gjre

Print ISSN 0975-5861

e-ISSN 2249-4596

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GJRE-C Classification: LCC: TP156.A3

Submission ReceivedFebruary 2, 2021
Peer Review Double Blind
Handling Editor
Accepted February 27, 2021
Published March 10, 2021

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November 27, 2023

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