Adsorption Kinetics of Sulfates by Anion Exchange Resin Containing Pristine Multiwalled Carbon Nano Tubes

Adsorption Kinetics of Sulfates by Anion Exchange Resin Containing Pristine Multiwalled Carbon Nano Tubes

Mahmoud Fathy

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Th. Abdel Moghny

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Ahmed E. Awadallah

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Abdel-Hameed A-A El-Bellihi

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α Egyptian Petroleum Research Institute

Adsorption Kinetics of Sulfates by Anion Exchange Resin Containing Pristine Multiwalled Carbon Nano Tubes

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Abstract

Since the documented discovery of carbon nanotubes (CNT) in 1991 by Iijima and the realization of their unique physical properties, including mechanical, thermal, and electrical, many investigators have endeavored to fabricate advanced CNT composite materials that exhibit one or more of these properties. The sulfates removal from synthetic water by High cross-linked polystyrene diviniyl benzene resin containing pristine multiwalled carbon nano tubes was studied at batch experiments in this study. The effect of pH, contact time, sulfates concentration and adsorbent dose on the sulfates sequestration was investigated. The optimum conditions were studied on Saline water as a case study. The results showed that with increasing of the absorbent amount; contact time and pH improve the efficiency of sulfates removal. The maximum sulfates uptake was obtained in pH and contact time 3.0 and 120 min, respectively. Also, with increasing initial concentration of sulfates in water, the efficiency of sulfates removal decreased. The obtained results in this study were matched with freundlich isotherm and pseudo second order kinetic. The maximum adsorption capacity (Xm or K) and constant rate were found 0.024 (mg/g) and 2.083 (mg/g.min), respectively. This study also showed that in the optimum conditions, the sulfates removal efficiency from Saline water by 0.1 mg/L sulfates was 85.64%. Eventually, High cross-linked polystyrene diviniyl benzene resin containing pristine multiwalled carbon nano tubes is recommended as a suitable and low cost absorbent to sulfates removal from aqueous solutions.

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

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No ethics committee approval was required for this article type.

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Not applicable for this article.

How to Cite This Article

Mahmoud Fathy. 2014. \u201cAdsorption Kinetics of Sulfates by Anion Exchange Resin Containing Pristine Multiwalled Carbon Nano Tubes\u201d. Global Journal of Research in Engineering - C: Chemical Engineering GJRE-C Volume 14 (GJRE Volume 14 Issue C1): .

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GJRE Volume 14 Issue C1
Pg. 21- 26

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Journal Specifications

Crossref Journal DOI 10.17406/gjre

Print ISSN 0975-5861

e-ISSN 2249-4596

Keywords

adsorption freundlich isotherm hard langmuir isotherm nano water

Submission ReceivedDecember 14, 2013
Peer Review Double Blind
Handling Editor
Accepted January 4, 2014
Published January 15, 2014

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v1.2

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June 2, 2014

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Article Matrices

Total Score: 104

Country: Egypt

Subject: Global Journal of Research in Engineering - C: Chemical Engineering

Authors: Mahmoud Fathy, Th. Abdel Moghny, Ahmed E. Awadallah, Abdel-Hameed A-A El-Bellihi (PhD/Dr. count: 0)

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