Chemical and Electrochemical Study on the Effectively of Melilotus Officinalis Extract as save Corrosion Inhibitor for Aluminium in 1 M Hydrochloric Acid Solutions

α
A. S. Fouda
A. S. Fouda
σ
A.S.Fouda
A.S.Fouda
ρ
Abd El-Aziz S.Fouda
Abd El-Aziz S.Fouda
Ѡ
Rabab Abo-shohba
Rabab Abo-shohba
¥
Walaa M. Husien
Walaa M. Husien
§
Esraa S. Ahmed
Esraa S. Ahmed
α Delta Higher Institute for Engineering and Technology, Egypt

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Chemical and Electrochemical Study on the Effectively of Melilotus Officinalis Extract as save Corrosion Inhibitor for Aluminium in 1 M Hydrochloric Acid Solutions

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Chemical and Electrochemical Study on the Effectively of Melilotus Officinalis Extract as save Corrosion Inhibitor for Aluminium in 1 M Hydrochloric Acid Solutions Banner

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Abstract

Melilotus officinalis Extract (MOE), was investigated as a green corrosion inhibitor for aluminium in 1 M HCl solution using weight loss, hydrogen evolution, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. Surface morphology was tested using scanning electron microscope (SEM). The effect of the temperature on corrosion behavior with addition of different concentrations was studied in the temperature range of 25-45 ºC by weight loss method. Polarization curves reveal that the investigated extract is a mixed type inhibitor. The inhibition efficiency was found to increase with increase in the investigated extract concentration and increase with increase in solution temperature. The adsorption of the inhibitor on aluminium surface was found to obey the Temkin’s adsorption isotherm. The activation and adsorption parameters were calculated and discussed. The results obtained from chemical and electrochemical techniques are in good agreement.

References

62 Cites in Article
  1. G Trabanelli (1991). Unknown Title.
  2. D Singh,A Dey (1993). Unknown Title.
  3. G Banerjee,S Malhotra (1992). Unknown Title.
  4. S Arab,E Noor (1993). Inhibition of Acid Corrosion of Steel by Some S-Alkylisothiouronium Iodides.
  5. I Raspini (1993). Influence of Sodium Salts of Organic Acids as Additives on Localized Corrosion of Aluminum and Its Alloys.
  6. A Khadraoui,A Khelifa,H Hamitouche,R Mehdaoui (2013). Inhibitive effect by extract of Mentha rotundifolia leaves on the corrosion of steel in 1 M HCl solution.
  7. M Elachouri,M Hajji,M Salem,S Kertit,R Coudert,E M Essassi (1995). Unknown Title.
  8. H Luo,Y Guan,K Han (1998). Unknown Title.
  9. M Migahed,E Azzam,A Al-Sabagh (2004). Corrosion inhibition of mild steel in 1 M sulfuric acid solution using anionic surfactant.
  10. Ruth Villamil,Paola Corio,Silvia Agostinho,Joel Rubim (1999). Effect of sodium dodecylsulfate on copper corrosion in sulfuric acid media in the absence and presence of benzotriazole.
  11. Hari Kumar,S Karthikeyan (2012). 925 Chemical Shifts and Coupling Constants for C9H6F10NO5P.
  12. Z Hadi,Alaa Al-Sawaad,Al-Mubarak,M Athir,Haddadi (2010). Unknown Title.
  13. Abd El Rehim,S Hassan,H Amin,M (2003). Unknown Title.
  14. Rong Guo,Tianqing Liu,Xun Wei (2002). Effects of SDS and some alcohols on the inhibition efficiency of corrosion for nickel.
  15. V Branzoi,F Golgovici,F Branzoi (2002). Unknown Title.
  16. K Parikh,K Joshi (2004). Unknown Title.
  17. S Al-Mhyawi (2014). Corrosion Inhibition of Aluminum in 0.5 M HCl by Garlic Aqueous Extract.
  18. A Ali,N Foaud (2012). Unknown Title.
  19. O Nwosu,E Osarolube,L Nnanna,C Akoma,T Chigbu (2014). Unknown Title.
  20. A James,O Akaranta (2009). Unknown Title.
  21. Nicole Kresge,Robert Simoni,Robert Hill /5% "Hemorrhagic Sweet Clover Disease, Dicumarol, and Warfarin: the Work of Karl Paul Link.
  22. (2014). Botanical Society of Britain and Ireland.
  23. B Abd-El-Nabey,A Abdel-Gaber,M Ali,E Khamis,S El-Housseiny (2013). Inhibitive Action of Cannabis Plant Extract on the Corrosion of Copper in 0.5 M H2SO4.
  24. A Onuchukwu,A Adamu (1998). The kinetics and mechanism of hydrogen evolution on corroding aluminum in alkaline medium.
  25. El Sheikh,M El Hassan,G El Tayeb,A Abdallah,A Antoun,M (1982). Studies on Sudanese medicinal plants III: indigenous Hyoscyamusmuticus as possible commercial source for hyoscyamine.
  26. M Eeva,J Salo,K Oksman-Caldentey (1998). Unknown Title.
  27. G Mu,T Zhao,M Liu,T Gu (1996). Unknown Title.
  28. R Parr,R Donnelly,M Levy,W Palke (1978). Unknown Title.
  29. R Bosch,J Hubrecht,W Bogaerts,B Syrett (2001). Electrochemical Frequency Modulation: A New Electrochemical Technique for Online Corrosion Monitoring.
  30. Da-Quan Zhang,Qi-Rui Cai,Xian-Ming He,Li-Xin Gao,Gui Kim (2009). Corrosion inhibition and adsorption behavior of methionine on copper in HCl and synergistic effect of zinc ions.
  31. H Lee,K Nobe (1986). Unknown Title.
  32. Z Tao,S Zhang,W Li,B Hou (2009). Unknown Title.
  33. E Ferreira,C Giacomelli,F Giacomelli,A Spinelli (2004). Evaluation of the inhibitor effect of l-ascorbic acid on the corrosion of mild steel.
  34. T Paskossy (1994). Unknown Title.
  35. F Growcock,J Jasinski (1989). Unknown Title.
  36. S Abdel-Rehim,K Khaled,N Abd-Elshafi (2006). Electrochemical frequency modulation as a new technique for monitoring corrosion inhibition of iron in acid media by new thiourea derivative.
  37. M Metikos,R Hukovic,Z Bobic,S Gwabac (1994). Unknown Title.
  38. A Caprani,I Epelboin,P Morel (1975). Valence de dissolution du titane en milieu sulfurique fluoré.
  39. J Bessone,C Mayer,Tuttnerk,W Lorenz (1983). Unknown Title.
  40. I Epelboin,M Keddam,H Takenouti (1972). Use of impedance measurements for the determination of the instant rate of metal corrosion.
  41. A Benedeti,P Sumodjo,K Nobe,P Cabot,W Proud (1995). Electrochemical studies of copper, copper-aluminium and copper-aluminium-silver alloys: Impedance results in 0.5M NaCl.
  42. H Ma,S Chen,L Niu,S Zhao,S Li,D Li (2002). Unknown Title.
  43. Xiang-Hong Li,Shu-Duan Deng,Hui Fu (2010). Inhibition by Jasminum nudiflorum Lindl. leaves extract of the corrosion of cold rolled steel in hydrochloric acid solution.
  44. M Lagrenee,B Mernari,M Bouanis,M Traisnel,F Bentiss (2002). Unknown Title.
  45. E Kus,F Mansfeld (2006). Unknown Title.
  46. Gregori Caignan,Sara Metcalf,Elizabeth Holt (2000). Thiophene substituted dihydropyridines.
  47. S Abdel-Rehim,K Khaled,N Abd-Elshafi (2006). Unknown Title.
  48. J Bockris,D Swinkels (1964). Adsorption of n-Decylamine on Solid Metal Electrodes.
  49. W Lorenz,F Mansfeld (1981). Unknown Title.
  50. A Yurt,G Bereket,A Kivrak,A Balaban,B (2005). Unknown Title.
  51. F Bentiss,M Traisnel,M Lagrenee (2000). Unknown Title.
  52. Mahmoud Saleh,Asem Atia (2006). Effects of structure of the ionic head of cationic surfactant on its inhibition of acid corrosion of mild steel.
  53. L Narv�ez,E Cano,D Bastidas (2005). 3-Hydroxybenzoic acid as AISI 316L stainless steel corrosion inhibitor in a H2SO4?HF?H2O2 pickling solution.
  54. Xianghong Li,Shuduan Deng,Hui Fu (2009). Synergism between red tetrazolium and uracil on the corrosion of cold rolled steel in H2SO4 solution.
  55. I Putilova,S Balezin,Y Barasanik (1960). Metallic Corrosion Inhibitors.
  56. V Saliyan,A Adhikari (2007). Unknown Title.
  57. Y Li,P Zhao,Q Liang,B Hou (2005). Unknown Title.
  58. A Mehaute,G Grepy (1989). Unknown Title.
  59. V Brusic,M Frisch,B Eldridge,F Novak,F Kaufman,B Rush,G Frankel (1991). Copper Corrosion With and Without Inhibitors.
  60. M Antonijevic,M Petrovic (2008). Unknown Title.
  61. M Musiani,G Mengoli (1987). Unknown Title.
  62. G Lewis (1978). The Adsorption of Benzotriazole Onto Cuprous Oxide Surface: An Electrode Impedance Study.

Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

A. S. Fouda. 2016. \u201cChemical and Electrochemical Study on the Effectively of Melilotus Officinalis Extract as save Corrosion Inhibitor for Aluminium in 1 M Hydrochloric Acid Solutions\u201d. Global Journal of Research in Engineering - C: Chemical Engineering GJRE-C Volume 15 (GJRE Volume 15 Issue C3): .

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Journal Specifications

Crossref Journal DOI 10.17406/gjre

Print ISSN 0975-5861

e-ISSN 2249-4596

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GJRE-C Classification: FOR Code: 290699
Version of record

v1.2

Issue date

January 9, 2016

Language
en
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Published Article

Melilotus officinalis Extract (MOE), was investigated as a green corrosion inhibitor for aluminium in 1 M HCl solution using weight loss, hydrogen evolution, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. Surface morphology was tested using scanning electron microscope (SEM). The effect of the temperature on corrosion behavior with addition of different concentrations was studied in the temperature range of 25-45 ºC by weight loss method. Polarization curves reveal that the investigated extract is a mixed type inhibitor. The inhibition efficiency was found to increase with increase in the investigated extract concentration and increase with increase in solution temperature. The adsorption of the inhibitor on aluminium surface was found to obey the Temkin’s adsorption isotherm. The activation and adsorption parameters were calculated and discussed. The results obtained from chemical and electrochemical techniques are in good agreement.

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Chemical and Electrochemical Study on the Effectively of Melilotus Officinalis Extract as save Corrosion Inhibitor for Aluminium in 1 M Hydrochloric Acid Solutions

A.S.Fouda
A.S.Fouda
Abd El-Aziz S.Fouda
Abd El-Aziz S.Fouda
Rabab Abo-shohba
Rabab Abo-shohba
Walaa M. Husien
Walaa M. Husien
Esraa S. Ahmed
Esraa S. Ahmed

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