Corrosion Inhibition of Mild Steel in Aqueous Solutions using Nonionic Surfactants

Corrosion Inhibition of Mild Steel in Aqueous Solutions using Nonionic Surfactants

A. S. Fouda

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A. S Fouda

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A. M. Attia

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A.M. Rashed

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α Delta Higher Institute for Engineering and Technology, Egypt

Corrosion Inhibition of Mild Steel in Aqueous Solutions using Nonionic Surfactants

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Abstract

The inhibiting effect of nonionic surfactant of Tween-20 and 60 on the corrosion of mild steel in 0.5 M HCl was studied by weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM).techniques The results show that inhibition efficiency increases with increasing the inhibitor concentration, while it decreases with increasing the temperature. The adsorption of Tweens on the mild steel surface obeys the Langmuir adsorption isotherm. The effect of temperature on the corrosion behavior of mild steel was also studied at four temperatures ranging from 25 to 55ºC the thermodynamic parameters were calculated and discussed. The values of free energy of adsorption for investigated Tweens were calculated. It was found the adsorption process is spontaneous and increases, in the same direction as inhibition efficiency. Polarization curves show that Tween-20 and 60 is mixed-type inhibitors but the cathode is more polarized than the anode. The results obtained from chemical and electrochemical techniques are in good agreement.

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How to Cite This Article

A. S. Fouda. 2015. \u201cCorrosion Inhibition of Mild Steel in Aqueous Solutions using Nonionic Surfactants\u201d. Global Journal of Research in Engineering - C: Chemical Engineering GJRE-C Volume 14 (GJRE Volume 14 Issue C3): .

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GJRE Volume 14 Issue C3
Pg. 21- 33

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Journal Specifications

Crossref Journal DOI 10.17406/gjre

Print ISSN 0975-5861

e-ISSN 2249-4596

Keywords

corrosion inhibition hcl Mild steel tween 20 and 60

Submission ReceivedDecember 15, 2013
Peer Review Double Blind
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Accepted January 1, 2014
Published January 15, 2014

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Article Matrices

Total Score: 103

Country: Egypt

Subject: Global Journal of Research in Engineering - C: Chemical Engineering

Authors: A. S Fouda, A. M. Attia, A.M. Rashed (PhD/Dr. count: 0)

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