Effect of Cadmium ion on Adsorption-Desorption Behavior of Simazine on Agricultural Soils

1
Dr. Rounak M. Shariff
Dr. Rounak M. Shariff
2
Rounak M. Shariff
Rounak M. Shariff
3
Media A. Hassan
Media A. Hassan
1 University of Salahaddin-Erbil, College of Science,Department of Chemistry,Kurdistan Region, Iraq

Send Message

To: Author

GJSFR Volume 13 Issue B6

Article Fingerprint

ReserarchID

C1Y41

Effect of Cadmium ion on Adsorption-Desorption Behavior of Simazine on Agricultural Soils Banner
  • English
  • Afrikaans
  • Albanian
  • Amharic
  • Arabic
  • Armenian
  • Azerbaijani
  • Basque
  • Belarusian
  • Bengali
  • Bosnian
  • Bulgarian
  • Catalan
  • Cebuano
  • Chichewa
  • Chinese (Simplified)
  • Chinese (Traditional)
  • Corsican
  • Croatian
  • Czech
  • Danish
  • Dutch
  • Esperanto
  • Estonian
  • Filipino
  • Finnish
  • French
  • Frisian
  • Galician
  • Georgian
  • German
  • Greek
  • Gujarati
  • Haitian Creole
  • Hausa
  • Hawaiian
  • Hebrew
  • Hindi
  • Hmong
  • Hungarian
  • Icelandic
  • Igbo
  • Indonesian
  • Irish
  • Italian
  • Japanese
  • Javanese
  • Kannada
  • Kazakh
  • Khmer
  • Korean
  • Kurdish (Kurmanji)
  • Kyrgyz
  • Lao
  • Latin
  • Latvian
  • Lithuanian
  • Luxembourgish
  • Macedonian
  • Malagasy
  • Malay
  • Malayalam
  • Maltese
  • Maori
  • Marathi
  • Mongolian
  • Myanmar (Burmese)
  • Nepali
  • Norwegian
  • Pashto
  • Persian
  • Polish
  • Portuguese
  • Punjabi
  • Romanian
  • Russian
  • Samoan
  • Scots Gaelic
  • Serbian
  • Sesotho
  • Shona
  • Sindhi
  • Sinhala
  • Slovak
  • Slovenian
  • Somali
  • Spanish
  • Sundanese
  • Swahili
  • Swedish
  • Tajik
  • Tamil
  • Telugu
  • Thai
  • Turkish
  • Ukrainian
  • Urdu
  • Uzbek
  • Vietnamese
  • Welsh
  • Xhosa
  • Yiddish
  • Yoruba
  • Zulu

The effect of cadmium (Cd) on adsorptiondesorption behavior of Simazine [2-chloro-4, 6 bis (ethylamine)-1,3,5-triazine] which is anionic herbicide were investigated at three different temperature 10, 25 and 40 ±1˚C on six agricultural soil samples which has different texture. The first order rate law was most fitted with the best correlation factor, the Linear, Freundlich and Langmuir models also were applied to describe the adsorption-desorption affinities to the soil samples. Values of adsorption rate constant k a were in the range 0.836 -1.818 h -1 while desorption rate constant k des were in the range 0.779 -1.376 h -1 . The activation energy E a * for adsorption processes followed the range 11.041-17.684 KJmol -1 . Values of equilibrium constant lnK o were in the range 0.048 -0.278. The standard free energy change ΔG o values were in the range -0.126 to -0.655 KJmol -1 . Values of the standard enthalpy change ΔH o followed the range -2.702 to -4.850 KJmol -1 . The value of standard entropy change ΔS o followed the range-7.557 to-14.965 Jmol -1 k -1 . The negative values revealed that the adsorption-desorption processes spontaneously, exothermic and physical in nature to some extent and chemical in others.

38 Cites in Articles

References

  1. R Kookana,R Gerritse,L Aylmore (1990). Effect of organic co-solvent on adsorption and desorption of Linuron and Simazine in soil.
  2. J Pignatello,B Xing (1996). Mechanisms of slow sorption of organic chemicals to natural particles.
  3. S Mitic,V Zivanovic,G Mileic (2002). A Kinetic Method for the Determination of Herbicide Simazine.
  4. E Morillo,T Undabeytia,C Maqueda,A Ramos (2000). Glyphosate adsorption on soils of different characteristics..
  5. Garrison Sposito (1994). Chemical Equilibrium And Kinetics.
  6. Rounakm. Shariff,Kafiam. Shareef (2011). Adsorption of Herbicides on eight Agricultural Soils.
  7. J Hamaker (1967). The Application of Mathematical Modeling to the Soil Persistence and Accumulation of Pesticides.
  8. M Kishk,M Abu-Sharar,M Bakry,B Abu-Donia (1979). Sorption-Desorption Characteristics of Methyl-Parathion by Clays.
  9. Thanh Dao (2003). Competitive Anion Sorption Effects on Dairy West Water Dissolved phosphorus Extraction with Zeolite-based Sorbents.
  10. Yong‐hak Kim,Thomas Heinze,Seong‐jae Kim,Carl Cerniglia (2004). Adsorption and Clay‐Catalyzed Degradation of Erythromycin A on Homoionic Clays.
  11. Washington Braida,Joseph Pignatello,Yuefeng Lu,Peter Ravikovitch,Alexander Neimark,Baoshan Xing (2003). Sorption Hysteresis of Benzene in Charcoal Particles.
  12. L Cox,R Celis,M Hermosine,J Cornejo (2000). Natural soil colloids to retard simazine and 2,4-D leaching in soil.
  13. M Rounak,Media Shariff,Hassan (2012). Kinetic study of adsorption-desorption of Simazine on Agricultural soils.
  14. Zhen-Li He,Hai-Ping Xu,Ying-Mei Zhu,Xiao-E Yang (2005). Adsorption-Desorption Characteristics of Cadmium in variable charge soils.
  15. M Rounak,Narmeen Shariff,Abdulla Abdulla,Yaba (2011). Adsorption-desorption study of surfacetants on Six Agricultural Soils.
  16. Ladlslau Martin-Neto,Eni Vleira,Garrison Sposlto (1994). Mechanism of Atrazine sorption by humic acid: A spectroscopic study.
  17. A Mohammed,Peter Ali,Baugh (2003). Sorption, Desorption Studies of Six Pyerethroids and Mirex on Soils using GC/ MS-NICI" Internet.
  18. G Suman,V Gajbhiye (2002). Adsorption-Desorption, Persistence, and Leaching Behavior of Dithiopyr in an Auvial soil of India.
  19. M Andrades,M Rodríguez-Cruz,M Sánchez-Martín,Maria Sánchez-Camazano (2004). Effect of the modification of natural clay minerals with hexadecylpyridinium cation on the adsorption–desorption of fungicides.
  20. Op Banasal (2004). Kinetics of interaction of three carbamate pesticides with Indian soils: Aligrah district.
  21. R Griffin,J Jurinak (1973). Test of a New Model for the Kinetics of Adsorption-Desorption Processes.
  22. A Elsayed,A Elkhatib,N Mahdy,Bbrakat (2007). Thermodynamics of Copper Desorption from Soils as Affected by Citrate and Succinate.
  23. K Chaudhary,B Prasad (1999). Thermodynamics of Potassiume Exchange Reaction in Entisol and vertisol using a Kinetic Approach by Miscible Displacement Technique.
  24. D Sparks,W Liebhardt (1983). TEMPERATURE EFFECTS ON POTASSIUM EXCHANGE AND SELECTIVITY IN DELAWARE SOILS.
  25. T Sismanoglu,A Ercag,S Pura,E Ercag (2004). Kinetics and isotherms of dazomet adsorption on natural adsorbents.
  26. F Lindistrom,R Haque,W Coshow (1970). Adsorption from Solution. III Anew Model for Kinetics of Adsorption -Desorption Processes.
  27. (1993). Prevention, Pesticides and Toxic Substances.
  28. Hongxia Zhu,H Selim (2000). HYSTERETIC BEHAVIOR OF METOLACHLOR ADSORPTION-DESORPTION IN SOILS.
  29. H Gupta,P Devprakash,Ishra,Pathak (2004). Studies on the Kinetics and Thermodynamics of Adsorption of Cypermethrin on Montmorillonite Clays.
  30. Michael Sander,Yuefeng Lu,Joseph Pignatello (2005). A Thermodynamically Based Method to Quantify True Sorption Hysteresis.
  31. G Alexandre,Andreia Prado,Glaudio Tosta,Airoldi (2004). Asorption, Separation, and Thermodynamic Data on Herbicide Picloram Anshored on Silica Gel and its Cation Interaction Behavior.
  32. Roger Swanson,Gordon Dutt (1973). Chemical and Physical Processes that Affect Atrazine and Distribution in Soil Systems.
  33. L Hundal,N Pasricha (1994). Thermodynamic Parameters of Potassium Exchange as Characterized by Equilibrium and Kinetic Approaches in Chloride and Perchlorate Background Anions.
  34. J Alam,A Dikshit,M Opadhayay (2005). Evaluation of Thermodynamic Properties of Sorption of 2, 4-D and Atrazine by Trirubber Gramules.
  35. Cass Miller,Joseph Pedlt (1992). Sorption-Desorption Hysteresis and Abiotic Degradation of Lindane in a Surface Material.
  36. Stephen Scribner,Thomas Benzing,Shaobai Sun,Stephen Boyd (1992). Desorption and Bioavailability of Aged Simazine Residues in Soil from a Continuous Corn Field.
  37. Hideyuki Katsumata,Satoshi Kaneco,Tohru Suzuki,Kiyohisa Ohta (2006). Determination of atrazine and simazine in water samples by high-performance liquid chromatography after preconcentration with heat-treated diatomaceous earth.
  38. Hrissi Karapanagioti,Sybille Kleineidam,David Sabatini,Peter Grathwohl,Bertrand Ligouis (2000). Impacts of Heterogeneous Organic Matter on Phenanthrene Sorption: Equilibrium and Kinetic Studies with Aquifer Material.

Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

Dr. Rounak M. Shariff. 2013. \u201cEffect of Cadmium ion on Adsorption-Desorption Behavior of Simazine on Agricultural Soils\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 13 (GJSFR Volume 13 Issue B6): .

Download Citation

Issue Cover
GJSFR Volume 13 Issue B6
Pg. 61- 71
Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Classification
Not Found
Version of record

v1.2

Issue date

September 21, 2013

Language

English

Experiance in AR

The methods for personal identification and authentication are no exception.

Read in 3D

The methods for personal identification and authentication are no exception.

Article Matrices
Total Views: 4741
Total Downloads: 2485
2026 Trends
Research Identity (RIN)
Related Research

Published Article

The effect of cadmium (Cd) on adsorptiondesorption behavior of Simazine [2-chloro-4, 6 bis (ethylamine)-1,3,5-triazine] which is anionic herbicide were investigated at three different temperature 10, 25 and 40 ±1˚C on six agricultural soil samples which has different texture. The first order rate law was most fitted with the best correlation factor, the Linear, Freundlich and Langmuir models also were applied to describe the adsorption-desorption affinities to the soil samples. Values of adsorption rate constant k a were in the range 0.836 -1.818 h -1 while desorption rate constant k des were in the range 0.779 -1.376 h -1 . The activation energy E a * for adsorption processes followed the range 11.041-17.684 KJmol -1 . Values of equilibrium constant lnK o were in the range 0.048 -0.278. The standard free energy change ΔG o values were in the range -0.126 to -0.655 KJmol -1 . Values of the standard enthalpy change ΔH o followed the range -2.702 to -4.850 KJmol -1 . The value of standard entropy change ΔS o followed the range-7.557 to-14.965 Jmol -1 k -1 . The negative values revealed that the adsorption-desorption processes spontaneously, exothermic and physical in nature to some extent and chemical in others.

Our website is actively being updated, and changes may occur frequently. Please clear your browser cache if needed. For feedback or error reporting, please email [email protected]
×

This Page is Under Development

We are currently updating this article page for a better experience.

Request Access

Please fill out the form below to request access to this research paper. Your request will be reviewed by the editorial or author team.
X

Quote and Order Details

Contact Person

Invoice Address

Notes or Comments

This is the heading

Lorem ipsum dolor sit amet, consectetur adipiscing elit. Ut elit tellus, luctus nec ullamcorper mattis, pulvinar dapibus leo.

High-quality academic research articles on global topics and journals.

Effect of Cadmium ion on Adsorption-Desorption Behavior of Simazine on Agricultural Soils

Rounak M. Shariff
Rounak M. Shariff
Media A. Hassan
Media A. Hassan

Research Journals