Effect of Cadmium ion on Adsorption-Desorption Behavior of Simazine on Agricultural Soils

Rounak M. Shariff

Effect of Cadmium ion on Adsorption-Desorption Behavior of Simazine on Agricultural Soils

Rounak M. Shariff * §

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§ University of Salahaddin-Erbil, College of Science, ...

Effect of Cadmium ion on Adsorption-Desorption Behavior of Simazine on Agricultural Soils

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Abstract

The effect of cadmium (Cd) on adsorptiondesorption behavior of Simazine [2-chloro-4, 6 bis (ethylamine)-1,3,5-triazine] which is anionic herbicide were investigated at three different temperature 10, 25 and 40 ±1˚C on six agricultural soil samples which has different texture. The first order rate law was most fitted with the best correlation factor, the Linear, Freundlich and Langmuir models also were applied to describe the adsorption-desorption affinities to the soil samples. Values of adsorption rate constant k a were in the range 0.836 -1.818 h -1 while desorption rate constant k des were in the range 0.779 -1.376 h -1 . The activation energy E a * for adsorption processes followed the range 11.041-17.684 KJmol -1 . Values of equilibrium constant lnK o were in the range 0.048 -0.278. The standard free energy change ΔG o values were in the range -0.126 to -0.655 KJmol -1 . Values of the standard enthalpy change ΔH o followed the range -2.702 to -4.850 KJmol -1 . The value of standard entropy change ΔS o followed the range-7.557 to-14.965 Jmol -1 k -1 . The negative values revealed that the adsorption-desorption processes spontaneously, exothermic and physical in nature to some extent and chemical in others.

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

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How to Cite This Article

Rounak Shariff. 2013. "Effect of Cadmium ion on Adsorption-Desorption Behavior of Simazine on Agricultural Soils". Global Journal of Science Frontier Research, Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 13 (GJSFR Volume 13 Issue B6).

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GJSFR Volume 13 Issue B6

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords

Adsorption- desorption isotherms simazine thermodynamic parameter UV-spectrophotometer

Classification

GJSFR-B Classification FOR Code: 961499

300103

Submission ReceivedJuly 20, 2013
Peer Review Double Blind
Handling Editor
Accepted August 19, 2013
Published August 30, 2013

Version of record

v1.2

Issue date

September 21, 2013

Language

English

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Total Score: 146

Country: Iraq

Subject: Global Journal of Science Frontier Research

Authors: Rounak M. Shariff, Media A. Hassan (PhD/Dr. count: 0)

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