Effect of Intercalation OF LiAl on Cation Distribution and Properties of Fe2TiO5.

α
S.S.Gurav
S.S.Gurav
σ
S.V. Salvi
S.V. Salvi
ρ
S.Y. Shingare
S.Y. Shingare
Ѡ
A.H. Karande
A.H. Karande
α University of Mumbai University of Mumbai

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Effect of Intercalation OF LiAl on Cation Distribution and Properties of Fe2TiO5.

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Abstract

In order to study the effect of intercalation of LiAl on the cation distribution and properties of Fe 2 TiO 5 , the samples are prepared by standard ceramic technique. The singlephase formation of the pseudobrookite is confirmed by XRD technique. The retention of amount and proportion of LiAl in the ceramics is confirmed by ICP technique. The ac and dc resistivity of the ceramic increases considerably whereas the interfacial contribution to the dielectric constant decreases by intercalation of LiAl. The experimental data of relaxation spectra, variation of dielectric constant and resistivity with temperature is analyzed and correlated. The magnetic hysteresis and susceptibility measurement shows that LiAl enhances the long range magnetic ordering. The proposed empirical model determines the cation distribution of the samples using lattice parameters.

References

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

S.S.Gurav. 2014. \u201cEffect of Intercalation OF LiAl on Cation Distribution and Properties of Fe2TiO5.\u201d. Global Journal of Science Frontier Research - A: Physics & Space Science GJSFR-A Volume 14 (GJSFR Volume 14 Issue A4): .

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Issue Cover
GJSFR Volume 14 Issue A4
Pg. 13- 17
Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords
Version of record

v1.2

Issue date

August 22, 2014

Language
en
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In order to study the effect of intercalation of LiAl on the cation distribution and properties of Fe 2 TiO 5 , the samples are prepared by standard ceramic technique. The singlephase formation of the pseudobrookite is confirmed by XRD technique. The retention of amount and proportion of LiAl in the ceramics is confirmed by ICP technique. The ac and dc resistivity of the ceramic increases considerably whereas the interfacial contribution to the dielectric constant decreases by intercalation of LiAl. The experimental data of relaxation spectra, variation of dielectric constant and resistivity with temperature is analyzed and correlated. The magnetic hysteresis and susceptibility measurement shows that LiAl enhances the long range magnetic ordering. The proposed empirical model determines the cation distribution of the samples using lattice parameters.

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Effect of Intercalation OF LiAl on Cation Distribution and Properties of Fe2TiO5.

S.S.Gurav
S.S.Gurav University of Mumbai
S.V. Salvi
S.V. Salvi
S.Y. Shingare
S.Y. Shingare
A.H. Karande
A.H. Karande

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