Electrochemical Behaviour of a Copper Electrode in Ammonium Sulfide Solution

Article ID

XEOH8

Electrochemical Behaviour of a Copper Electrode in Ammonium Sulfide Solution

Dr. I. Zaafarany
Dr. I. Zaafarany Umm Al-Qura University
Herbert Boller
Herbert Boller
DOI

Abstract

The electrochemical behaviour of a copper electrode in ammonium sulphide solutions was studied using cyclic voltammogrammetry and potentiostatic and galvanostatic polarization techniques. The morphology and composition of the layers formed on the copper electrode were studied by scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDAX) and X-ray powder diffractometry. Besides different binary copper sulphide phases the ternary phases NH4Cu7-xS4 and NH4CuS4 were observed, NH4Cu7-xS4 crystallizing as needles perpendicular to the electrode surface.

Electrochemical Behaviour of a Copper Electrode in Ammonium Sulfide Solution

The electrochemical behaviour of a copper electrode in ammonium sulphide solutions was studied using cyclic voltammogrammetry and potentiostatic and galvanostatic polarization techniques. The morphology and composition of the layers formed on the copper electrode were studied by scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDAX) and X-ray powder diffractometry. Besides different binary copper sulphide phases the ternary phases NH4Cu7-xS4 and NH4CuS4 were observed, NH4Cu7-xS4 crystallizing as needles perpendicular to the electrode surface.

Dr. I. Zaafarany
Dr. I. Zaafarany Umm Al-Qura University
Herbert Boller
Herbert Boller

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Dr. I. Zaafarany. 2012. “. Global Journal of Science Frontier Research – B: Chemistry GJSFR-B Volume 12 (GJSFR Volume 12 Issue B2): .

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Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

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Electrochemical Behaviour of a Copper Electrode in Ammonium Sulfide Solution

Dr. I. Zaafarany
Dr. I. Zaafarany Umm Al-Qura University
Herbert Boller
Herbert Boller

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