Emulsion Terpolymerization of St/MMA/BuA: III. Modeling of BuA Backbiting, Diffusion of Monomers and Polymers in the Particle, and BuA Induced Branching

Emulsion Terpolymerization of St/MMA/BuA: III. Modeling of BuA Backbiting, Diffusion of Monomers and Polymers in the Particle, and BuA Induced Branching

Javier Alejandro Diaz Ponce

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Javier Alejandro DAaz Ponce

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Carlos MartAnez Vera

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Universidad Autónoma Metropolitana

Emulsion Terpolymerization of St/MMA/BuA: III. Modeling of BuA Backbiting, Diffusion of Monomers and Polymers in the Particle, and BuA Induced Branching

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Abstract

In this work, the BuA backbiting and its kp-gel effect is included in a previous published model for the simulation of the emulsion terpolymerization of St/MMA/BuA. It is then possible to evaluate the branching of this terpolymer and the average diffusion of the monomers, polymers and polymer radicals. The diffusion is evaluated through the propagation and termination coefficients with a modification of the Schmoluchowski equation. On the other hand, it is also found that the BuA propagation coefficient depends on the fraction of BuA free volume X Vf,BuA in the terpolymer and that the kind of model suitable for the simulation of the k p -gel effect is determined by the rate of polymerization R p , the number of radicals in the particle per mol of monomers #R/n and the total diffusion of the polymer radicals in the particle n T D PR .

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

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How to Cite This Article

Javier Alejandro Diaz Ponce. 2017. \u201cEmulsion Terpolymerization of St/MMA/BuA: III. Modeling of BuA Backbiting, Diffusion of Monomers and Polymers in the Particle, and BuA Induced Branching\u201d. Global Journal of Research in Engineering - C: Chemical Engineering GJRE-C Volume 17 (GJRE Volume 17 Issue C3): .

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GJRE Volume 17 Issue C3
Pg. 45- 74

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Journal Specifications

Crossref Journal DOI 10.17406/gjre

Print ISSN 0975-5861

e-ISSN 2249-4596

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GJRE-C Classification: FOR Code: 290699

Submission ReceivedDecember 15, 2016
Peer Review Double Blind
Handling Editor
Accepted January 3, 2017
Published January 15, 2017

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November 3, 2017

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Article Matrices

Total Score: 104

Country: Mexico

Subject: Global Journal of Research in Engineering - C: Chemical Engineering

Authors: Javier Alejandro DAaz Ponce, Carlos MartAnez Vera, Carlos MartAnez Vera, Carlos MartAnez Vera (PhD/Dr. count: 0)

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