Extractive Demetalization of Iraqi Crude Oil by using Zeolite A

Luma H. Mahmood; Mohammad Abid

Extractive Demetalization of Iraqi Crude Oil by using Zeolite A

Luma H. Mahmood * §

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Mohammad F. Abid

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§ Department of Chemical Engineering, University of Te...

Extractive Demetalization of Iraqi Crude Oil by using Zeolite A

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Abstract

The feasibility of removal vanadium (V) from Iraqi crude oil using zeolite A was investigated. Different operating parameters such as adsorbent loading, vanadium loading, and operating time were studied for their effects on metal removal efficiency. Experimental results of adsorption test show that Langmuir isotherm predicts well the experimental data and the maximum zeolite A uptake of V was 30 mg/g. XRD and EDX analyses revealed the noticeable uptake of zeolite for V. In crude oil, experimental results indicated that for zeolite loading at 1g/100ml oil and within approximately 5 h, the removal efficiencies of V were 60, 45, and 33% at vanadium loadings of 75, 85, and 95 ppm respectively. While at 10, 20, 40, and 50 h the removal efficiency was 68, 75, 78 and 78% for 75 ppm of V loading. The equilibrium concentration of V in crude oil was attained after 40 h of operation. Long term tests revealed the high stability of zeolite A for vanadium removal. Results depict that zeolite A could be advantageous for removal of V in the crude oil hydrotreating units.

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

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How to Cite This Article

Luma H. Mahmood, Mohammad F. Abid. 2019. "Extractive Demetalization of Iraqi Crude Oil by using Zeolite A". Global Journal of Research in Engineering - C: Chemical Engineering GJRE-C Volume 19 (GJRE Volume 19 Issue C1).

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GJRE Volume 19 Issue C1

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Journal Specifications

Crossref Journal DOI 10.17406/gjre

Print ISSN 0975-5861

e-ISSN 2249-4596

Keywords

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Classification

GJRE-C Classification FOR Code: 090499

Submission ReceivedDecember 8, 2018
Peer Review Double Blind
Handling Editor
Accepted January 2, 2019
Published January 15, 2019

Version of record

v1.2

Issue date

January 21, 2019

Language

English

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Article Matrices

Total Score: 102

Country: Iraq

Subject: Global Journal of Research in Engineering - C: Chemical Engineering

Authors: Luma H. Mahmood, Mohammad F. Abid (PhD/Dr. count: 0)

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Publish Date: 2019 01, Tue

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