FTIR and Optical Absorption Studies Of New Magnesium Lead Borate Glasses

Dr. G. Ramadevudu; M.Narasimha Chary

FTIR and Optical Absorption Studies Of New Magnesium Lead Borate Glasses

Dr. G. Ramadevudu * § M.Sc, Ph.D

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M.Narasimha Chary

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§ Osmania University, Hyderabad, India.

FTIR and Optical Absorption Studies Of New Magnesium Lead Borate Glasses

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Abstract

New magnesium lead borate glasses (10-x) MgO-xMgCl2-40PbO-50B2O3 (x = 0, 1, 2, 3, 4, 5, 6, 7, 8, and 10 mole%) were prepared by melt quenching technique. Fourier transform infrared spectroscopic studies revealed the presence of BO3 trigonal and BO4 tetrahedral structural units in these glasses. The optical energy band gaps, Urbach energies and theoretical refractive index values are reported. No considerable structural changes with the composition are observed. FTIR revealed the formation of NBOs and the behaviour of MgO as glass network modifier. The expansion of B-O network with increasing x mole% is attributed to the presence of Chlorine ions.

Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

Dr. Ramadevudu, M.Narasimha Chary. 2012. "FTIR and Optical Absorption Studies Of New Magnesium Lead Borate Glasses". Global Journal of Science Frontier Research, Global Journal of Science Frontier Research - A: Physics & Space Science GJSFR-A Volume 12 (GJSFR Volume 12 Issue A4).

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords

glass network formers glass network modifiers infrared spectroscopy optical energy band gap Urbach energy

Classification

GJSFR-A Classification FOR Code: 020503

020504

020401

Submission ReceivedMay 26, 2012
Peer Review Double Blind
Handling Editor
Accepted June 16, 2012
Published June 26, 2012

Version of record

v1.2

Issue date

July 7, 2012

Language

English

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Article Matrices

Total Score: 154

Country: India

Subject: Global Journal of Science Frontier Research

Authors: Dr. G. Ramadevudu, S.Lakshmi Srinivasa Rao, Md. Shareeffuddin, M.Narasimha Chary, M.Lakshmipathi Rao (PhD/Dr. count: 1)

View Count (all-time): 252

Total Views (Real + Logic): 2048

Total Downloads (simulated): 155

Publish Date: 2012 06, Tue

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Total Views: 2K

Total Downloads: 155

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