Gas Chromatographic Investigations of Composition of Spent Tyre Pyrolysis Gasoline

Antoaneta Pavlova; Dicho Stratiev; Ivelina Shishkova; Magdalena Mitkova; Milcho Skumov; Tania Tzaneva

Gas Chromatographic Investigations of Composition of Spent Tyre Pyrolysis Gasoline

Antoaneta Pavlova §

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Dicho Stratiev ‡

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Ivelina Shishkova ¶

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Magdalena Mitkova ‖

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Milcho Skumov ‖

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Tania Tzaneva ‖

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§ LUKOIL Neftochim Burgas, Burgas, Bulgaria

‡ Chief Process Engineer Department, Lukoil Neftohim B...

¶ Research Laboratory, Lukoil Neftohim Burgas, Burgas ...

‖ University Assen Zlatarov, Burgas 8010, Bulgaria

Gas Chromatographic Investigations of Composition of Spent Tyre Pyrolysis Gasoline

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Abstract

This paper describes a case study in which multiple analytical techniques were used to identify and characterize the composition of spent tyre pyrolysis gasoline obtained from the tyre pyrolysis process. The objective of the study was to describe the spent tyre pyrolysis gasoline and determine its suitable commercial application. The analytical techniques used for analyses of spent tyre pyrolysis gasoline included gas chromatography-mass spectrometry, gas chromatography with sulfur-chemilumin- escence detector and capillary gas chromatography with flame-ionization detector. Examination of the chemical composition of the spent tyre pyrolysis gasoline showed that nearly 90 % of the sample composition is established. Generally, aromatic hydrocarbons and naphthenes are the dominating compounds detected in the spent tyre pyrolysis gasoline obtained from tyres pyrolysis. The content of individual sulfur compounds is also measured. Compared to similar researches only the alkylthiols are identified. The spent tyre pyrolysis gasoline comprise mainly of compounds that are similar to pyrolysis gasoline from naphtha stream cracking, fluid catalytic cracking (FCC) gasoline and straight run naphtha. The spent tyre pyrolysis gasoline has high sulfur content what is a reason to make it directly used inapplicable. The straight run naphtha and pyrolysis gasoline from naphtha stream cracking have lowest content of sulfur and the spent tyre pyrolysis gasoline could be blended with the fluid catalytic cracking (FCC) gasoline for hydrotreatment. Also the spent tyre pyrolysis gasoline could be blended with the straight run naphtha to catalytic reforming unit for further processing.

References

18 Cites in Article

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

Antoaneta Pavlova, Dicho Stratiev, Ivelina Shishkova, Magdalena Mitkova, Milcho Skumov, Tania Tzaneva. 2013. "Gas Chromatographic Investigations of Composition of Spent Tyre Pyrolysis Gasoline". Global Journal of Medical Research - K: Interdisciplinary GJMR-K Volume 13 (GJMR Volume 13 Issue 14 (K4)).

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GJMR Volume 13 Issue 14 (K4)

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Journal Specifications

Crossref Journal DOI 10.17406/gjmra

Print ISSN 0975-5888

e-ISSN 2249-4618

Keywords

fluid catalytic cracking (FCC) gasoline GC - SCD GC-FID GC/MS pyrolysis gasoline from naphtha stream cracking spent tyre pyrolysis gasoline straight run naphtha

Classification

GJMR-K Classification NLMC Code: QY 130

WI 500

Submission ReceivedDecember 8, 2012
Peer Review Double Blind
Handling Editor
Accepted January 3, 2013
Published May 30, 2013

Version of record

v1.2

Issue date

May 30, 2013

Language

English

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Article Matrices

Total Score: 106

Country: Bulgaria

Subject: Global Journal of Medical Research - K: Interdisciplinary

Authors: Antoaneta Pavlova, Dicho Stratiev, Ivelina Shishkova, Magdalena Mitkova, Milcho Skumov, Tania Tzaneva (PhD/Dr. count: 0)

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