Glutathione@Fe3O4 Nanoparticles as Efficient Material for the Adsorption of Mercury(II) from Water At Low Concentrations

Glutathione@Fe3O4 Nanoparticles as Efficient Material for the Adsorption of Mercury(II) from Water At Low Concentrations

Wilfredo Marimón-Bolívar

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Edgar E. González

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Pontificia Universidad Javeriana

Glutathione@Fe3O4 Nanoparticles as Efficient Material for the Adsorption of Mercury(II) from Water At Low Concentrations

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Abstract

The application of magnetic nanoparticles (MNPs) in environmental and chemical engineering is progressively increasing, leading to the development of new surface modifications using green methodologies. Magnetite nanoparticles functionalized with Glutathione (Glutathione@MNPs) were synthesized by a novel eco-friendly method using glutathione as a reductant and stabilizer agent.Mercury adsorption was investigated at different initial pH values, contact time, temperatures and adsorbate-adsorbent concentrations. Maximum Hg2+ removal took place at pH 7.5. Adsorption dynamic data were best described by pseudo-second order rate equation, and adsorption equilibrium data were best fitted to Langmuir equation.Maximum adsorption capacities of 34.48 mg/g at 1 mg/L of initial conditions and 25°C was obtained. Regeneration of Glutathione@MNPs and recovery of Hg2+ was demonstrated using 0.1 M KI and HCl up to ten cycles of adsorption.

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How to Cite This Article

Wilfredo Marimón-Bolívar. 2019. \u201cGlutathione@Fe3O4 Nanoparticles as Efficient Material for the Adsorption of Mercury(II) from Water At Low Concentrations\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 19 (GJSFR Volume 19 Issue B1).

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Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

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GJSFR-B Classification FOR Code: 030299

Submission ReceivedDecember 29, 2018
Peer Review Double Blind
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Accepted January 28, 2019
Published February 11, 2019

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February 16, 2019

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Total Score: 102

Country: Colombia

Subject: Global Journal of Science Frontier Research - B: Chemistry

Authors: Wilfredo Marimón-Bolívar, Edgar E. González (PhD/Dr. count: 0)

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