Leave-Intercalation Theory and Conductive Mechanism during Charge-Discharge Process for Secondary Battery

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Chuan-Zheng Yang
Chuan-Zheng Yang
1 Shanghai University

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The source of conductive ions in the charge and discharge process of AB 5 / β -Ni(OH) 2 , 2H-graphite/ LiMeO 2 and 2H-graphite/LiFePO 4 batteries is thought to be provided by the phase transition of positive active materials, so it is called phase transition theory. Through the detailed study of the charge and discharge processes of AB 5 / β -Ni(OH) 2 , 2H-graphite/ Li(Ni 1/3 Co 1/3 Mn 1/3 )O 2 and 2H-graphite/LiFePO 4 , it is found that the source of conductive ions is the deintercalation of H (nickel-hydrogen battery) and Li (lithium-ion battery) in positive and negative active materials, and the de-intercalation theory is proposed. On this basis, the conductive mechanisms of these three types of batteries are clarified: The directional migration and movement of conductive ions under the action of electric field.

Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

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No ethics committee approval was required for this article type.

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Not applicable for this article.

Chuan-Zheng Yang. 2026. \u201cLeave-Intercalation Theory and Conductive Mechanism during Charge-Discharge Process for Secondary Battery\u201d. Global Journal of Science Frontier Research - A: Physics & Space Science GJSFR-A Volume 23 (GJSFR Volume 23 Issue A6): .

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Alternative: Exploring Charge and Conductive Mechanisms in Secondary Battery Materials.
Issue Cover
GJSFR Volume 23 Issue A6
Pg. 45- 60
Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

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GJSFR-A Classification: LCC: TK2941 .D432
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v1.2

Issue date

August 25, 2023

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English

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The source of conductive ions in the charge and discharge process of AB 5 / β -Ni(OH) 2 , 2H-graphite/ LiMeO 2 and 2H-graphite/LiFePO 4 batteries is thought to be provided by the phase transition of positive active materials, so it is called phase transition theory. Through the detailed study of the charge and discharge processes of AB 5 / β -Ni(OH) 2 , 2H-graphite/ Li(Ni 1/3 Co 1/3 Mn 1/3 )O 2 and 2H-graphite/LiFePO 4 , it is found that the source of conductive ions is the deintercalation of H (nickel-hydrogen battery) and Li (lithium-ion battery) in positive and negative active materials, and the de-intercalation theory is proposed. On this basis, the conductive mechanisms of these three types of batteries are clarified: The directional migration and movement of conductive ions under the action of electric field.

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Leave-Intercalation Theory and Conductive Mechanism during Charge-Discharge Process for Secondary Battery

Chuan-Zheng Yang
Chuan-Zheng Yang Shanghai University

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