Preparation, Characterisation and Reactions of Stable Adducts of TRIS (Pentafluorophenyl) Antimony (V) Diisothiocyanates.

Article ID

L90I7

Preparation, Characterisation and Reactions of Stable Adducts of TRIS (Pentafluorophenyl) Antimony (V) Diisothiocyanates.

Ram Nath Prasad Yadav
Ram Nath Prasad Yadav Tribhuvan University
DOI

Abstract

A series of new stable adducts of tris (pentafluo-rophenyl)antimony(V) diisothiocyante of the type (C6H5)3 Sb(NCS)2.L. Where, L = dipropyl formamide (DPF), 3-methylpyridine(3-Picoline), dimethyl formamide (DMF), tryphenylphosphine oxide(Ph3PO), triphenylarsine oxide (Ph3AsO), dimethyl sulfoxide (DMSO), thiourea (TU), pyridine(C5H5N) have been synthesized by the reaction of tris (pentafluorophenyl)antimony(V) diisothiocyanate with desired ligand in anhydrous methanol. Tris(pentafluorophenyl) antimony diisothiocyanate was obtained by the metathetical reaction of tris(pentafluorophenyl) antimony (V) dichloride and potassium thiocyanate in anhydrous methanol. The molecular weight measurement and molar conductance data of the complexes revealed them to be monomeric and non-conducting in nature. Elemental analysis and IR data indicates that the complexes have hexacoordinated octahedral structure.

Preparation, Characterisation and Reactions of Stable Adducts of TRIS (Pentafluorophenyl) Antimony (V) Diisothiocyanates.

A series of new stable adducts of tris (pentafluo-rophenyl)antimony(V) diisothiocyante of the type (C6H5)3 Sb(NCS)2.L. Where, L = dipropyl formamide (DPF), 3-methylpyridine(3-Picoline), dimethyl formamide (DMF), tryphenylphosphine oxide(Ph3PO), triphenylarsine oxide (Ph3AsO), dimethyl sulfoxide (DMSO), thiourea (TU), pyridine(C5H5N) have been synthesized by the reaction of tris (pentafluorophenyl)antimony(V) diisothiocyanate with desired ligand in anhydrous methanol. Tris(pentafluorophenyl) antimony diisothiocyanate was obtained by the metathetical reaction of tris(pentafluorophenyl) antimony (V) dichloride and potassium thiocyanate in anhydrous methanol. The molecular weight measurement and molar conductance data of the complexes revealed them to be monomeric and non-conducting in nature. Elemental analysis and IR data indicates that the complexes have hexacoordinated octahedral structure.

Ram Nath Prasad Yadav
Ram Nath Prasad Yadav Tribhuvan University

No Figures found in article.

Ram Nath Prasad Yadav. 2014. “. Global Journal of Science Frontier Research – B: Chemistry GJSFR-B Volume 14 (GJSFR Volume 14 Issue B3): .

Download Citation

Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Classification
Not Found
Article Matrices
Total Views: 4508
Total Downloads: 2303
2026 Trends
Research Identity (RIN)
Related Research
Our website is actively being updated, and changes may occur frequently. Please clear your browser cache if needed. For feedback or error reporting, please email [email protected]

Request Access

Please fill out the form below to request access to this research paper. Your request will be reviewed by the editorial or author team.
X

Quote and Order Details

Contact Person

Invoice Address

Notes or Comments

This is the heading

Lorem ipsum dolor sit amet, consectetur adipiscing elit. Ut elit tellus, luctus nec ullamcorper mattis, pulvinar dapibus leo.

High-quality academic research articles on global topics and journals.

Preparation, Characterisation and Reactions of Stable Adducts of TRIS (Pentafluorophenyl) Antimony (V) Diisothiocyanates.

Ram Nath Prasad Yadav
Ram Nath Prasad Yadav Tribhuvan University

Research Journals