Quick Simultaneous Determination of NMP and DMAC in Synthetic Fibers by Py-GC-MS using a Thermal Desorption Function

Eun Kyung Choe; Moon Hwan Song; Young Dal Cho

Quick Simultaneous Determination of NMP and DMAC in Synthetic Fibers by Py-GC-MS using a Thermal Desorption Function

Eun Kyung Choe * §

Contact

Moon Hwan Song

Contact

Young Dal Cho

Contact

Korea Institute of Industrial Technology

Quick Simultaneous Determination of NMP and DMAC in Synthetic Fibers by Py-GC-MS using a Thermal Desorption Function

Article Fingerprint

ReserarchID

UI4F9

Quick Simultaneous Determination of NMP and DMAC in Synthetic Fibers by Py-GC-MS using a Thermal Desorption Function Banner

Key Research Insights

Synthesized scholarly intelligence & interactive research assistant

Abstract

The simultaneous analyses of NMP and DMAc in synthetic fibers that have been regulated recently due to their human hazard properties were studied by both a conventional GC-MS method and a thermal desorption(TD)-GC-MS method that uses Py-GC-MS instrument using the thermal desorption function. Method validation characteristics such as linearity, precision of peak area and retention time, limit of quantification on their determination using a new TD-GC-MS method were found to be acceptable according to the well-recognized method validation guidelines and the current regulation limit. Recovery ratios of DMAc from the spiked synthetic fibers were estimated to be 95.2% to 97.1% with Soxhlet extraction using methanol as measured by GC-MS. Residual amounts of NMP and DMAc in commercial meta-aramid, polyester, and spandex fibers were measured by and GC-MS and TD-GC-MS, respectively and showed a good correlation between two methods with the ratio of 85.5% to 119%. Results of this study suggested that the TD-GC-MS analysis can provide both a good screening and a quick determination of NMP and DMAc in synthetic fibers without any solvent extraction of fiber samples that is a routine and time consuming pretreatment in the conventional GC-MS analysis.

References

24 Cites in Article

Reference Format

Lirong Yao,Changhwan Lee,Jooyong Kim (2010). Fabrication of electrospun meta-aramid nanofibers in different solvent systems.
N-Methyl-2-Pyrrolidone, Application data sheet prepared by LyondellBasell.
V Gabara,J Hartzler,K Lee,D Rodini,H Yang (1001). Handbook of Fiber Chemistry.
M Headinger,E Rudisill,D Luckey (2010). Snapshot: Pam Rudisill, MSN, MEd, RN, NEA-BC.
T Tai,J Masson,D Rodini,R Leonard (1997). Corrections to EP A and B documents on the internet.
R Robello,F Calenti,D Jahi,Č,M Miku (2013). Unknown Title.
N,N-Dimethylaceamide areas of application prepared by BASF.
Steven Vaughan (2011). The European Chemicals Agency and ECHA guidance.
Mouna Zachary,Ann Gebhart,Margaret Whittaker (2011). GreenScreen® for Safer Chemicals, as a support tool for the EU reach regulation: Identifying chemicals of very high concern (SVHC) and safer alternatives.
Candidate list of substances of very high concern for authorization.
The reporting list of chemicals of high concern to children (CHCC list), CSPA(Children's Safe Product Act) reporting rule prepared.
® Oeko-Tex (2012). German legislation on azo dyes and Oeko-Tex Standard 100.
Oeko-Tex ® Standard (2014). German legislation on azo dyes and Oeko-Tex Standard 100.
Phillip Borman,David Elder (2005). Q2(R1) Validation of Analytical Procedures.
(2009). Guidance for the Validation of Analytical Methodology and Calibration of Equipment used for Testing of Illicit Drugs in Seized Materials and Biological Specimens.
Y Juillet,C Dubois,F Bintein,J Dissard,A Bossée (2014). Unknown Title.
K Han,J Zhang,P Wargocki,H Knudsen,B Guo (2010). Determination of material emission signatures by PTR-MS and their correlations with odor assessments by human subjects.
(1110). Test Methods for Analyzing Organic Contaminants on Silicon Wafer Surfaces by Thermal Desorption Gas Chromatography.
M Song,Y Cho,E Choe (2014). Unknown Title.
Isabel Taverniers,Marc De Loose,Erik Van Bockstaele (2004). Trends in quality in the analytical laboratory. II. Analytical method validation and quality assurance.
L Huber (2007). Validation and Qualification in Analytical Laboratories.
Yukihiro Ouchi,Hiroyuki Yanagisawa,Shigehiko Fujimaki (2019). Evaluating Phthalate Contaminant Migration Using Thermal Desorption–Gas Chromatography–Mass Spectrometry (TD–GC–MS).
T Yuzawa,C Watanabe,R Freeman,S Tsuge (2009). Unknown Title.
Astm D (2013). Test Method for Determination of Low Level, Regulated Phthalates in Poly (Vinyl Chloride) Plastics by Thermal Desorption--Gas Chromatography/Mass Spectrometry.

Download References

Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

Eun Kyung Choe, Moon Hwan Song, Young Dal Cho. 2016. "Quick Simultaneous Determination of NMP and DMAC in Synthetic Fibers by Py-GC-MS using a Thermal Desorption Function". Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 16 (GJSFR Volume 16 Issue B1).

More Citation Formats

Select Citation Style:

Download Citation

GJSFR Volume 16 Issue B1

Explore Journals Explore Volume Read This Issue

Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords

Not Found

Classification

GJSFR-B Classification FOR Code: 030699

Submission ReceivedDecember 23, 2015
Peer Review Double Blind
Handling Editor
Accepted January 20, 2016
Published February 4, 2016

Version of record

v1.2

Issue date

March 1, 2016

Language

English

Experiance in AR

Explore published articles in an immersive Augmented Reality environment. Our platform converts research papers into interactive 3D books, allowing readers to view and interact with content using AR and VR compatible devices.

View in VR

Read in 3D

Your published article is automatically converted into a realistic 3D book. Flip through pages and read research papers in a more engaging and interactive format.

View in 3D

Article Matrices

Total Score: 178

Country: South Korea

Subject: Global Journal of Science Frontier Research

Authors: Kwang Seo Park, Moon Hwan Song, Young Dal Cho, Eun Kyung Choe (PhD/Dr. count: 0)

View Count (all-time): 294

Total Views (Real + Logic): 795

Total Downloads (simulated): 71

Publish Date: 2016 02, Thu

Monthly Totals (Real + Logic):

Month 1: 18 views
Month 2: 48 views
Month 3: 65 views
Month 4: 34 views
Month 5: 56 views
Month 6: 31 views
Month 7: 32 views
Month 8: 39 views
Month 9: 33 views
Month 10: 33 views
Month 11: 41 views
Month 12: 39 views
Month 13: 31 views
Month 14: 35 views
Month 15: 36 views
Month 16: 43 views
Month 17: 19 views
Month 18: 27 views
Month 19: 37 views
Month 20: 38 views
Month 21: 45 views
Month 22: 35 views
Month 23: 25 views
Month 24: 25 views
Month 25: 24 views
Month 26: 25 views
Month 27: 13 views
Month 28: 39 views
Month 29: 37 views
Month 30: 18 views
Month 31: 21 views
Month 32: 30 views
Month 33: 14 views
Month 34: 40 views
Month 35: 15 views
Month 36: 17 views
Month 37: 37 views
Month 38: 13 views
Month 39: 27 views
Month 40: 46 views
Month 41: 33 views
Month 42: 30 views
Month 43: 40 views
Month 44: 32 views
Month 45: 40 views
Month 46: 44 views
Month 47: 17 views
Month 48: 35 views
Month 49: 36 views
Month 50: 31 views
Month 51: 24 views
Month 52: 46 views
Month 53: 22 views
Month 54: 39 views
Month 55: 30 views
Month 56: 34 views
Month 57: 40 views
Month 58: 28 views
Month 59: 27 views
Month 60: 33 views
Month 61: 40 views
Month 62: 41 views
Month 63: 24 views
Month 64: 24 views
Month 65: 30 views
Month 66: 34 views
Month 67: 17 views
Month 68: 32 views
Month 69: 32 views
Month 70: 26 views
Month 71: 33 views
Month 72: 18 views
Month 73: 38 views
Month 74: 27 views
Month 75: 29 views
Month 76: 35 views
Month 77: 31 views
Month 78: 14 views
Month 79: 39 views
Month 80: 42 views
Month 81: 22 views
Month 82: 32 views
Month 83: 22 views
Month 84: 41 views
Month 85: 30 views
Month 86: 41 views
Month 87: 39 views
Month 88: 34 views
Month 89: 16 views
Month 90: 27 views
Month 91: 43 views
Month 92: 29 views
Month 93: 15 views
Month 94: 26 views
Month 95: 19 views
Month 96: 40 views
Month 97: 31 views
Month 98: 34 views
Month 99: 17 views
Month 100: 29 views
Month 101: 33 views
Month 102: 42 views
Month 103: 17 views
Month 104: 24 views
Month 105: 21 views
Month 106: 33 views
Month 107: 21 views
Month 108: 38 views
Month 109: 41 views
Month 110: 36 views
Month 111: 27 views
Month 112: 20 views
Month 113: 32 views
Month 114: 26 views
Month 115: 32 views
Month 116: 42 views
Month 117: 14 views
Month 118: 31 views
Month 119: 41 views
Month 120: 29 views
Month 121: 33 views
Month 122: 45 views
Month 123: 42 views
Month 124: 37 views
Month 125: 32 views
Month 126: 52 views
Month 127: 47 views
Month 128: 35 views

Total Views: 795

Total Downloads: 71

All Trends