Simulating the Second Moment of NMR Spectral line in Ammonium Chloride Single

1
F.I. Bashirov
F.I. Bashirov
2
N.K. Gaisin
N.K. Gaisin
1 Kazan Federal University

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Simulating the Second Moment of NMR Spectral line in Ammonium Chloride Single Banner
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Innovative technique of simulating the second moment of NMR spectral line broadened owing to the magnetic dipole-dipole interaction in crystals with internal molecular motion is suggested. The local hindered molecular motion (HMM) is approximated by the extended angular jump model. The resulting expression of the second moment allows one to evaluate the crystal structure distortion and the dynamical parameters of HMM. The presented theory agrees with the experimental anisotropic second moment of proton NMR spectral line in whole temperature region of the ammonium chloride single crystal investigation.

Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

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No ethics committee approval was required for this article type.

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Not applicable for this article.

F.I. Bashirov. 2017. \u201cSimulating the Second Moment of NMR Spectral line in Ammonium Chloride Single\u201d. Global Journal of Science Frontier Research - A: Physics & Space Science GJSFR-A Volume 17 (GJSFR Volume 17 Issue A1): .

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GJSFR Volume 17 Issue A1
Pg. 11- 25
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Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

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GJSFR-A Classification: FOR Code: 020399
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v1.2

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May 12, 2017

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English

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Innovative technique of simulating the second moment of NMR spectral line broadened owing to the magnetic dipole-dipole interaction in crystals with internal molecular motion is suggested. The local hindered molecular motion (HMM) is approximated by the extended angular jump model. The resulting expression of the second moment allows one to evaluate the crystal structure distortion and the dynamical parameters of HMM. The presented theory agrees with the experimental anisotropic second moment of proton NMR spectral line in whole temperature region of the ammonium chloride single crystal investigation.

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Simulating the Second Moment of NMR Spectral line in Ammonium Chloride Single

F.I. Bashirov
F.I. Bashirov Kazan Federal University
N.K. Gaisin
N.K. Gaisin

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