Spectroscopic Analysis of Chromium Soaps

α
S.K. Upadhyay
S.K. Upadhyay
σ
Vasu Mitra
Vasu Mitra
ρ
R.K.shukla
R.K.shukla
α Dr. A.P.J. Abdul Kalam Technical University

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Spectroscopic Analysis of Chromium Soaps

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Abstract

The spectroscopic characteristics of chromium soaps (butyrate and caprylate) in solid state were investigated by IR, X-ray diffraction and thermal measurements. The IR results reveal that the fatty acids exist in dimeric state through hydrogen bonding and soaps possess partial ionic character. The X-ray diffraction measurements were used to calculate the long spacings and the results confirm the double layer structure of chromium soaps. The decomposition reaction was found kinetically of zero order with energy of activation .275 and .180 kcal mol-1 for butyrate and caprylate, respectively.

References

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

S.K. Upadhyay. 2014. \u201cSpectroscopic Analysis of Chromium Soaps\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 14 (GJSFR Volume 14 Issue B4): .

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Version of record

v1.2

Issue date

August 16, 2014

Language
en
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The spectroscopic characteristics of chromium soaps (butyrate and caprylate) in solid state were investigated by IR, X-ray diffraction and thermal measurements. The IR results reveal that the fatty acids exist in dimeric state through hydrogen bonding and soaps possess partial ionic character. The X-ray diffraction measurements were used to calculate the long spacings and the results confirm the double layer structure of chromium soaps. The decomposition reaction was found kinetically of zero order with energy of activation .275 and .180 kcal mol-1 for butyrate and caprylate, respectively.

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Spectroscopic Analysis of Chromium Soaps

Vasu Mitra
Vasu Mitra
S.K. Upadhyay
S.K. Upadhyay Dr. A.P.J. Abdul Kalam Technical University
R.K.shukla
R.K.shukla

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