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The spectroscopic characteristics of chromium soaps (butyrate and caprylate) in solid state were investigated by IR, X-ray diffraction and thermal measurements. The IR results reveal that the fatty acids exist in dimeric state through hydrogen bonding and soaps possess partial ionic character. The X-ray diffraction measurements were used to calculate the long spacings and the results confirm the double layer structure of chromium soaps. The decomposition reaction was found kinetically of zero order with energy of activation .275 and .180 kcal mol-1 for butyrate and caprylate, respectively.
S.K. Upadhyay. 2014. \u201cSpectroscopic Analysis of Chromium Soaps\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 14 (GJSFR Volume 14 Issue B4): .
Crossref Journal DOI 10.17406/GJSFR
Print ISSN 0975-5896
e-ISSN 2249-4626
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Total Score: 103
Country: India
Subject: Global Journal of Science Frontier Research - B: Chemistry
Authors: Vasu Mitra, S.K. Upadhyay, R.K.shukla (PhD/Dr. count: 0)
View Count (all-time): 148
Total Views (Real + Logic): 4535
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Publish Date: 2014 08, Sat
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The spectroscopic characteristics of chromium soaps (butyrate and caprylate) in solid state were investigated by IR, X-ray diffraction and thermal measurements. The IR results reveal that the fatty acids exist in dimeric state through hydrogen bonding and soaps possess partial ionic character. The X-ray diffraction measurements were used to calculate the long spacings and the results confirm the double layer structure of chromium soaps. The decomposition reaction was found kinetically of zero order with energy of activation .275 and .180 kcal mol-1 for butyrate and caprylate, respectively.
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