Spectroscopic Studies on Ti3+-Doped Na2O-PbO-Al2O3-B2O3-SiO2 Glasses

Spectroscopic Studies on Ti3+-Doped Na2O-PbO-Al2O3-B2O3-SiO2 Glasses

Dr. Karumuri Vijaya Babu Head, Department of Physics, The Bapatla College of Arts & Sciences, Bapatla-522101 Andhra Pradesh India

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Spectroscopic Studies on Ti3+-Doped Na2O-PbO-Al2O3-B2O3-SiO2 Glasses

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Abstract

Na 2 O-PbO-Al 2 O 3 -B 2 O 3 -SiO 2 glasses doped with different concentrations of TiO 2 (ranging from 0 to 0.9 mol %) in steps of 0.3 mol % is synthesized by melt quenching method. The samples are characterized by X-ray diffraction (XRD), the powder XRD pattern of all the prepared samples con firms the amorphous nature of the glass. Thermal an alysis has been carried out for the prepared glasses, their glass transition temperature (T g ) and crystallization temperature (T c ) are evaluated using their Differential thermal analysis (DTA) profiles. Optical absorption and Fourier transform infrared (FT-IR) spectroscopic techniques have been studied. The UV-Vis absorption spectra of these glasses exhibit two resolved bands at about 691 nm and 832 nm due to 2 B 2g → 2 A 1g and 2 B 2g → 2 B 1g transitions of Ti 3+ ions. From the absorption spectra, the optical band gap and Urbach energies are evaluated. The FT-IR spectra has been carried out the existence of conventional and structural units of these prepared glasses. Various physical parameters and optical basicity are also evaluated with different concentrations of TiO 2 ions.

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No external funding was declared for this work.

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The authors declare no conflict of interest.

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How to Cite This Article

Dr. Karumuri Vijaya Babu. 2020. \u201cSpectroscopic Studies on Ti3+-Doped Na2O-PbO-Al2O3-B2O3-SiO2 Glasses\u201d. Global Journal of Science Frontier Research - A: Physics & Space Science GJSFR-A Volume 20 (GJSFR Volume 20 Issue A9).

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GJSFR Volume 20 Issue A9

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Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

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GJSFR-A Classification FOR Code: 020503

Submission ReceivedJune 6, 2020
Peer Review Double Blind
Handling Editor
Accepted July 2, 2020
Published July 13, 2020

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September 8, 2020

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