Synthesis and Applications of Isocyanate Free Polyurethane Materials

Thualfeqar G Mohammed
Thualfeqar G Mohammed
Mehdi Erfani Jazi
Mehdi Erfani Jazi
Fatemeh Aghabozorgi
Fatemeh Aghabozorgi
Universiti Teknologi Malaysia & University of Kufa

Send Message

To: Author

Synthesis and Applications of Isocyanate Free Polyurethane Materials

Article Fingerprint

ReserarchID

210O9

Synthesis and Applications of Isocyanate Free Polyurethane Materials Banner

AI TAKEAWAY

Connecting with the Eternal Ground
  • English
  • Afrikaans
  • Albanian
  • Amharic
  • Arabic
  • Armenian
  • Azerbaijani
  • Basque
  • Belarusian
  • Bengali
  • Bosnian
  • Bulgarian
  • Catalan
  • Cebuano
  • Chichewa
  • Chinese (Simplified)
  • Chinese (Traditional)
  • Corsican
  • Croatian
  • Czech
  • Danish
  • Dutch
  • Esperanto
  • Estonian
  • Filipino
  • Finnish
  • French
  • Frisian
  • Galician
  • Georgian
  • German
  • Greek
  • Gujarati
  • Haitian Creole
  • Hausa
  • Hawaiian
  • Hebrew
  • Hindi
  • Hmong
  • Hungarian
  • Icelandic
  • Igbo
  • Indonesian
  • Irish
  • Italian
  • Japanese
  • Javanese
  • Kannada
  • Kazakh
  • Khmer
  • Korean
  • Kurdish (Kurmanji)
  • Kyrgyz
  • Lao
  • Latin
  • Latvian
  • Lithuanian
  • Luxembourgish
  • Macedonian
  • Malagasy
  • Malay
  • Malayalam
  • Maltese
  • Maori
  • Marathi
  • Mongolian
  • Myanmar (Burmese)
  • Nepali
  • Norwegian
  • Pashto
  • Persian
  • Polish
  • Portuguese
  • Punjabi
  • Romanian
  • Russian
  • Samoan
  • Scots Gaelic
  • Serbian
  • Sesotho
  • Shona
  • Sindhi
  • Sinhala
  • Slovak
  • Slovenian
  • Somali
  • Spanish
  • Sundanese
  • Swahili
  • Swedish
  • Tajik
  • Tamil
  • Telugu
  • Thai
  • Turkish
  • Ukrainian
  • Urdu
  • Uzbek
  • Vietnamese
  • Welsh
  • Xhosa
  • Yiddish
  • Yoruba
  • Zulu
Font Type
Font Size
Font Size
Bedground

Abstract

The manufacture of conventional polyurethanes include the use of isocyanates, which in turn require using toxic and hazardous phosgene. The safety devices are necessary to prepare these monomers. Therefore, the huge investment is inevitable for this process. Also, these monomers cannot be considered as environmentally friendly chemicals. The increasing global awareness for protection of environment from chemical pollutants has created a necessary demand for environmentally benign products. The reaction of cyclic carbonates (polycarbonates) with amines results in formation of hydroxyurethanes that can be taken into account as a unique reaction. This specific reaction has been investigated over last few years. Most chemists have been strongly attracted by this technique that is due to its potential application to prepare the green, non-toxic, non-sensitive towards moisture isocyanate free polyurethanes.

References

88 Cites in Article
  1. B Burchardt (2010). 3 -Advances in polyurethane structural adhesives.
  2. G Bierwagen,A Huovinen (2010). Paint Formulation.
  3. (2010). Chapter 1 -Deposition Technologies: An Overview.
  4. J Dodge (2003). Polyurethanes and Polyureas.
  5. M Sonnenschein,W Koonce (2002). Encyclopedia of Polymer Science and Technology.
  6. G Ravi,G Achin,M Vijay (2010). Smart Polyurethane Surfaces from Tethered Dendritic Polyols.
  7. E Dyer,H Scott (1957). The Preparation of Polymeric and Cyclic Urethans and Ureas from Ethylene Carbonate and Amines.
  8. G Rokicki,A Piotrowska (2002). A new route to polyurethanes from ethylene carbonate, diamines and diols.
  9. L Ubaghs,N Fricke,H Keul,H Höcker (2004). Polyurethanes with Pendant Hydroxyl Groups: Synthesis and Characterization.
  10. P Lan,S Corneillie,E Schacht,M Davies,A Shard (1996). Synthesis and characterization of segmented polyurethanes based on amphiphilic polyether diols.
  11. V Malshe,M Mandlecha (2000). Production of butane 1-3 diol, propane 1-3 diol and other diols and polyols.
  12. Scott Guelcher,Katie Gallagher,Jonathan Didier,Derek Klinedinst,John Doctor,Aaron Goldstein,Garth Wilkes,Eric Beckman,Jeffrey Hollinger (2005). Synthesis of biocompatible segmented polyurethanes from aliphatic diisocyanates and diurea diol chain extenders.
  13. X Ma,J Yu,J Wan (2006). Urea and ethanolamine as a mixed plasticizer for thermoplastic starch.
  14. P Wang,S Liu,F Zhou,B Yang,A Alshammari,L Lu,Y Deng (2014). Twostep synthesis of dimethyl carbonate from urea, ethylene glycol and methanol using acid-base bifunctional zinc-yttrium oxides.
  15. B Bhanage,S Fujita,Y -I.; Ikushima,M Arai (2003). Transesterification of urea and ethylene glycol to ethylene carbonate as an important step for urea based dimethyl carbonate synthesis.
  16. B Ochiai,T Utsuno (2013). Non-isocyanate synthesis and application of telechelic polyurethanes via polycondensation of diurethanes obtained from ethylene carbonate and diamines.
  17. R Cotter,J Whelan (1963). Multiple cyclic carbonate polymers.
  18. J Guan,Y Song,Y Lin,X Yin,M Zuo,Y Zhao,X Tao,Q Zheng (2011). Progress in Study of Non-Isocyanate Polyurethane.
  19. G Rokicki,P Parzuchowski,M Mazurek (2015). Nonisocyanate polyurethanes: synthesis, properties, and applications.
  20. H Tomita,F Sanda,T Endo (2001). Self-Polyaddition of Six-Membered Cyclic Carbonate Having Fmoc-Protected Amino Group: Novel Synthetic Method of Polyhydroxyurethane.
  21. Tadashi Sakai,Nobuhiro Kihara,Takeshi Endo (1995). Polymer Reaction of Epoxide and Carbon Dioxide. Incorporation of Carbon Dioxide into Epoxide Polymers.
  22. L Han,H.-J Choi,S.-J Choi,B Liu,D.-W Park (2011). Ionic liquids containing carboxyl acid moieties grafted onto silica: Synthesis and application as heterogeneous catalysts for cycloaddition reactions of epoxide and carbon dioxide.
  23. Q Gong,H Luo,J Cao,Y Shang,H Zhang,W Wang,X Zhou (2012). Synthesis of Cyclic Carbonate From Carbon Dioxide and Epoxide Using Amino Acid Ionic Liquid Under 1 atm Pressure.
  24. M.-K Lee,H.-L Shim,M Dharman,K.-H Kim,S.-W Park,D.-W Park (2008). Synthesis of cyclic carbonate from allyl glycidyl ether and CO2 over silica-supported ionic liquid catalysts prepared by sol-gel method.
  25. K Roshan,G Mathai,J Kim,J Tharun,G.-A Park,D.-W Park (2012). A biopolymer mediated efficient synthesis of cyclic carbonates from epoxides and carbon dioxide.
  26. Rahul Watile,Krishna Deshmukh,Kishor Dhake,Bhalchandra Bhanage (2012). Efficient synthesis of cyclic carbonate from carbon dioxide using polymer anchored diol functionalized ionic liquids as a highly active heterogeneous catalyst.
  27. Y Ono (1997). Dimethyl carbonate for environmentally benign reactions.
  28. U Chatterjee,X Wang,S Jewrajka,M Soucek (2011). Polyester/Poly(meth)acrylate Block Copolymers by Combined Polycondensation/ATRP: Characterization and Properties.
  29. H Tomita,F Sanda,T Endo (2001). Structural analysis of polyhydroxyurethane obtained by polyaddition of bifunctional five-membered cyclic carbonate and diamine based on the model reaction.
  30. B Nohra,L Candy,J.-F Blanco,Y Raoul,Z Mouloungui (2012). Aminolysis Reaction of Glycerol Carbonate in Organic and Hydroorganic Medium.
  31. Krasimir Kossev,Neli Koseva,Kolio Troev (2003). Preparation of 4-hydroxy-methyl-1,3-dioxolan-2-one under phase transfer catalysis conditions.
  32. M Climent,A Corma,P De Frutos,S Iborra,M Noy,A Velty,P Concepción (2010). Chemicals from biomass: Synthesis of glycerol carbonate by transesterification and carbonylation with urea with hydrotalcite catalysts. The role of acid-base pairs.
  33. J Ochoa-Gómez,O Gómez-Jiménez-Aberasturi,B Maestro-Madurga,A Pesquera-Rodríguez,C Ramírez-López,L Lorenzo-Ibarreta,J Torrecilla-Soria,M Villarán-Velasco (2009). Synthesis of glycerol carbonate from glycerol and dimethyl carbonate by transesterification: Catalyst screening and reaction optimization.
  34. José Ochoa-Gómez,Olga Gómez-Jiménez-Aberasturi,Camilo Ramírez-López,Belén Maestro-Madurga (2012). Synthesis of glycerol 1,2-carbonate by transesterification of glycerol with dimethyl carbonate using triethylamine as a facile separable homogeneous catalyst.
  35. D Webster,A Crain (2000). Synthesis and applications of cyclic carbonate functional polymers in thermosetting coatings.
  36. E Beavers,J O'brien (1961). Acrylates and Methacrylates.
  37. D Webster (2003). Cyclic carbonate functional polymers and their applications.
  38. Joseph Judge,Charles Price (1959). The copolymerization characteristics of vinylene carbonate, γ‐crotonolactone and methyl bicyclo(2,2,1)‐2‐heptene‐5‐carboxylate.
  39. A.-A Shaikh,S Sivaram (1996). Organic Carbonates.
  40. A Takagaki,K Iwatani,S Nishimura,K Ebitani (2010). Synthesis of glycerol carbonate from glycerol and dialkyl carbonates using hydrotalcite as a reusable heterogeneous base catalyst.
  41. P Parzuchowski,M Jurczyk-Kowalska,J Ryszkowska,G Rokicki (2006). Epoxy resin modified with soybean oil containing cyclic carbonate groups.
  42. Sofia Benyahya,Myriam Desroches,Rémi Auvergne,Stéphane Carlotti,Sylvain Caillol,Bernard Boutevin (2011). Synthesis of glycerin carbonate-based intermediates using thiol–ene chemistry and isocyanate free polyhydroxyurethanes therefrom.
  43. Sang‐hyun Pyo,Rajni Hatti‐kaul (2012). Selective, Green Synthesis of Six‐Membered Cyclic Carbonates by Lipase‐Catalyzed Chemospecific Transesterification of Diols with Dimethyl Carbonate.
  44. J Wang,L He,X Dou,F Wu (2009). Poly(ethylene glycol): an Alternative Solvent for the Synthesis of Cyclic Carbonate from Vicinal Halohydrin and Carbon Dioxide.
  45. Y Sasaki (1986). Reaction of carbon dioxide with propargyl alcohol catalyzed by a combination of Ru3(CO)12 and Et3N.
  46. María Climent,Avelino Corma,Sara Iborra,Sergio Martínez‐silvestre,Alexandra Velty (2013). Preparation of Glycerol Carbonate Esters by using Hybrid Nafion–Silica Catalyst.
  47. C Tang,H Nulwala,K Damodaran,P Kaur,D Luebke (2011). Tunable poly(hydroxyl urethane) from CO2-Based intermediates using thiol-ene chemistry.
  48. O Figovsky,L Shapovalov (2003). Preparation of oligomeric cyclocarbonates and their use in ionisocyanate or hybrid nonisocyanate polyurethanes.
  49. O Figovsky,L Shapovalov (2007). Preparation of oligomeric cyclocarbonates and their use in ionisocyanate or hybrid nonisocyanate polyurethanes.
  50. X Wang,M Soucek (2013). Investigation of nonisocyanate urethane dimethacrylate reactive diluents for UV-curable polyurethane coatings.
  51. Z Hosgor,N Kayaman-Apohan,S Karatas,A Gungor,Y Menceloglu (2012). Nonisocyanate polyurethane/silica hybrid coatings via a sol-gel route.
  52. Fan Jia,Xiaoyu Chen,Yan Zheng,Yusheng Qin,Youhua Tao,Xianhong Wang (2015). One-pot atom-efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.
  53. Kenneth Doll,Sevim Erhan (2005). Synthesis of Carbonated Fatty Methyl Esters Using Supercritical Carbon Dioxide.
  54. I Javni,D Hong,Z Petrović (2008). Soy-based polyurethanes by nonisocyanate route.
  55. A Boyer,E Cloutet,T Tassaing,B Gadenne,C Alfos,H Cramail (2010). Solubility in CO2 and carbonation studies of epoxidized fatty acid diesters: towards novel precursors for polyurethane synthesis.
  56. M Bahr,A Bitto,R Mulhaupt (2012). Cyclic limonene dicarbonate as a new monomer for non-isocyanate oligo-and polyurethanes (NIPU) based upon terpenes.
  57. M Bähr,R Mühlhaupt,B Ritter (2012). Carbonate group comprising terpene-derived monomers and isocyanate-free polyurethanes.
  58. S Ghaffar,M Fan (2014). Lignin in straw and its applications as an adhesive.
  59. N Mahmood,Z Yuan,J Schmidt,C Xu (2013). Production of polyols via direct hydrolysis of kraft lignin: Effect of process parameters.
  60. Albert Lee,Yulin Deng (2015). Green polyurethane from lignin and soybean oil through non-isocyanate reactions.
  61. Q Chen,K Gao,C Peng,H Xie,Z Zhao,M Bao (2015). Preparation of lignin/glycerol-based bis(cyclic carbonate) for the synthesis of polyurethanes.
  62. O Türünç,N Kayaman-Apohan,M Kahraman,Y Menceloğlu,A Güngör (2008). Nonisocyanate based polyurethane/silica nanocomposites and their coating performance.
  63. S Stelzig,J Kempter,S Noerpel,J Klee,A Facher,U Walz,C Weber (2013). Composite filler particles and process for the preparation thereof.
  64. A.-C Albertson,M Sjoling (1992). Homopolymerization of 1,8Dioxan-2-one to High Molecular Weight Poly(Trimethylene Carbonate).
  65. Bassam Nohra,Laure Candy,Jean‐françois Blanco,Yann Raoul,Zephirin Mouloungui (2013). Synthesis of five and six‐membered cyclic glycerilic carbonates bearing exocyclic urethane functions.
  66. Sang-Hyun Pyo,Per Persson,Stefan Lundmark,Rajni Hatti-Kaul (2011). Solvent-free lipase-mediated synthesis of six-membered cyclic carbonates from trimethylolpropane and dialkyl carbonates.
  67. T Miyagawa,M Shimizu,F Sanda,T Endo (2005). Six-Membered Cyclic Carbonate Having Styrene Moiety as a Chemically Recyclable Monomer. Construction of Novel Cross-Linking-De-Cross-Linking System of Network Polymers.
  68. H Kricheldorf,B Weegen-Schulz (1995). Polymers of carbonic acid: 13. Polymerization of cyclotrimethylenecarbonate with tin tetrahalides.
  69. Nobukatsu Nemoto,Fumio Sanda,Takeshi Endo (2001). Cationic ring‐opening polymerization of six‐membered cyclic carbonates with ester groups.
  70. P Brignou,J.-F Carpentier,S Guillaume (2011). Metal-and Organo-Catalyzed Ring-Opening Polymerization of α-Methyl-Trimethylene Carbonate: Insights into the Microstructure of the Polycarbonate.
  71. J Matsuo,F Sanda,T Endo (1998). Cationic ringopening polymerization behavior of an aliphatic seven-membered cyclic carbonate, 1,3-dioxepan-2one.
  72. Cyclic Carbonates as Monomers for Phosgene-and Isocyanate-Free Polyurethanes and Polycarbonates.
  73. L Vogdanis,B Martens,H Uchtmann,F Hensel,W Heitz (1990). Synthetic and thermodynamic investigations in the polymerization of ethylene carbonate.
  74. H Tomita,H Hidaka,F Sanda,T Endo (2000). Synthesis of Polyhydroxyurethanes by Ring-opening Polyaddtion of Bi-functional Cyclic Carbonates with Diaminesandthe Film Properties.
  75. O Figovsky,L Shapovalov (2002). Features of reaction amino-cyclocarbonate for production of new type nonisocyanate polyurethane coatings.
  76. B Tamami,S Sohn,G Wilkes (2004). Incorporation of carbon dioxide into soybean oil and subsequent preparation and studies of nonisocyanate polyurethane networks.
  77. (null). Aerospace series. Paints and varnishes. Two component, cold curing polyurethane paint, anti slip.
  78. O Figovsky,L Shapovalov,F Buslov (2005). Ultraviolet and thermostable non-isocyanate polyurethane coatings.
  79. W Blank (1989). Certain hydroxyalkyl carbamates, polymers and uses thereof.
  80. P Forgione,B Singh (1992). Betahydroxyalkylcarbamyl-methylated aminotriazines.
  81. W Ho,L Capino,M Croyle,J Reuter,R Tomko (2008). Moisture cure non-isocyanate acrylic coatings.
  82. J Valentino,E Michael,D Robert (1997). Synthesis and Coating Properties of Novel Waterborne Polyurethane Dispersions.
  83. O Figovsky,L Sklyarsky,O Sklyarsky (2000). Polyurethane adhesives for electronic devices.
  84. O Birukov,O Figovsky,A Leykin,L Shapovalov (2011). Epoxy-amine composition modified with hydroxyalkyl urethane.
  85. Jing-Zhong Hwang,Shih-Chieh Wang,Po-Chen Chen,Chi-Yuan Huang,Jen-Taut Yeh,Kan-Nan Chen (2012). A new UV-curable PU resin obtained through a nonisocyanate process and used as a hydrophilic textile treatment.
  86. O Figovsky,L Shapovalov,O Axenov (2004). Advanced coatings based upon non-isocyanate polyurethanes for industrial applications.
  87. S Allauddin,R Narayan,K Raju (2013). Synthesis and Properties of Alkoxysilane Castor Oil and Their Polyurethane/Urea-Silica Hybrid Coating Films.
  88. M Kathalewar,A Sabnis,G Waghoo (2013). Effect of incorporation of surface treated zinc oxide on nonisocyanate polyurethane based nano-composite coatings.

Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

Thualfeqar G Mohammed. 2016. \u201cSynthesis and Applications of Isocyanate Free Polyurethane Materials\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 16 (GJSFR Volume 16 Issue B3).

Download Citation

Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords
Classification
GJSFR-B Classification FOR Code: 259999
Version of record

v1.2

Issue date
October 12, 2016

Language
en
Experiance in AR

Explore published articles in an immersive Augmented Reality environment. Our platform converts research papers into interactive 3D books, allowing readers to view and interact with content using AR and VR compatible devices.

Read in 3D

Your published article is automatically converted into a realistic 3D book. Flip through pages and read research papers in a more engaging and interactive format.

Article Matrices
Total Views: 3844
Total Downloads: 1816
2026 Trends
Related Research
Our website is actively being updated, and changes may occur frequently. Please clear your browser cache if needed. For feedback or error reporting, please email [email protected]

Request Access

Please fill out the form below to request access to this research paper. Your request will be reviewed by the editorial or author team.
X

Quote and Order Details

Contact Person

Invoice Address

Notes or Comments

This is the heading

Lorem ipsum dolor sit amet, consectetur adipiscing elit. Ut elit tellus, luctus nec ullamcorper mattis, pulvinar dapibus leo.

High-quality academic research articles on global topics and journals.

Synthesis and Applications of Isocyanate Free Polyurethane Materials

Mehdi Erfani Jazi
Mehdi Erfani Jazi
Thualfeqar G Mohammed
Thualfeqar G Mohammed <p>Universiti Teknologi Malaysia & University of Kufa</p>
Fatemeh Aghabozorgi
Fatemeh Aghabozorgi

Research Journals