Synthesis, Characterization and Biological Activities of Cu(II), Ni(II), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) Complexes with Schiff base Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate

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Sultana Shakila Khan
Sultana Shakila Khan
1 Pabna University of Science and Technology

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Synthesis, Characterization and Biological Activities of Cu(II), Ni(II), Zn(II), Cd(II), Sn(II), Co(II),  Sb(III) and Fe(III) Complexes with Schiff base Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate Banner
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The Complexes of Cu(II), Ni(II)), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) with Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate have been synthesized and characterized by elemental analysis, molar conductance, magnetic susceptibility, FT-IR, UV-Visible spectroscopy. The Schiff bases in every case behaved as bidentate, uninegative ligands. The complexes of Cu(II), Co(II) and Fe(III) are paramagnetic while all other complexes are diamagnetic. The complexes [Cu(C 11 H 11 N 2 S 2 ) 2 ] and [Ni(C 11 H 11 N 2 S 2 ) 2 ] had, square planar structures with two ligands satisfying the four steriochemical sites, where the complexes [Zn(C 11 H 11 N 2 S 2 ) 2 ] and [Cd(C 11 H 11 N 2 S 2 ) 2 ] were tetrahedral and the complexes [Sn(C 11 H 11 N 2 S 2 ) 2 (H 2 O) 2 ], [Co(C 11 H 11 N 2 S 2 ) 2 (H 2 O) 2 ], [Sb(C 11 H 11 N 2 S 2 ) 2 (NO 3 )(H 2 O)] and [Fe(C 11 H 11 N 2 S 2 ) 2 (NO 3 ) (H 2 O)] were octahedral in geometry. The metal complexes have been screened for their antibacterial activity.

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Funding

No external funding was declared for this work.

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The authors declare no conflict of interest.

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No ethics committee approval was required for this article type.

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Sultana Shakila Khan. 2013. \u201cSynthesis, Characterization and Biological Activities of Cu(II), Ni(II), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) Complexes with Schiff base Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 13 (GJSFR Volume 13 Issue B6): .

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GJSFR Volume 13 Issue B6
Pg. 15- 26
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Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

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September 21, 2013

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The Complexes of Cu(II), Ni(II)), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) with Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate have been synthesized and characterized by elemental analysis, molar conductance, magnetic susceptibility, FT-IR, UV-Visible spectroscopy. The Schiff bases in every case behaved as bidentate, uninegative ligands. The complexes of Cu(II), Co(II) and Fe(III) are paramagnetic while all other complexes are diamagnetic. The complexes [Cu(C 11 H 11 N 2 S 2 ) 2 ] and [Ni(C 11 H 11 N 2 S 2 ) 2 ] had, square planar structures with two ligands satisfying the four steriochemical sites, where the complexes [Zn(C 11 H 11 N 2 S 2 ) 2 ] and [Cd(C 11 H 11 N 2 S 2 ) 2 ] were tetrahedral and the complexes [Sn(C 11 H 11 N 2 S 2 ) 2 (H 2 O) 2 ], [Co(C 11 H 11 N 2 S 2 ) 2 (H 2 O) 2 ], [Sb(C 11 H 11 N 2 S 2 ) 2 (NO 3 )(H 2 O)] and [Fe(C 11 H 11 N 2 S 2 ) 2 (NO 3 ) (H 2 O)] were octahedral in geometry. The metal complexes have been screened for their antibacterial activity.

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Synthesis, Characterization and Biological Activities of Cu(II), Ni(II), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) Complexes with Schiff base Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate

Sultana Shakila Khan
Sultana Shakila Khan Pabna University of Science and Technology

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