Synthesis, Characterization and Biological Activities of Cu(II), Ni(II), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) Complexes with Schiff base Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate

Sultana Shakila Khan
Sultana Shakila Khan * §
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§ Pabna University of Science and Technology

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Synthesis, Characterization and Biological Activities of Cu(II), Ni(II), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) Complexes with Schiff base Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate

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Synthesis, Characterization and Biological Activities of Cu(II), Ni(II), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) Complexes with Schiff base Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate Banner

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Abstract

The Complexes of Cu(II), Ni(II)), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) with Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate have been synthesized and characterized by elemental analysis, molar conductance, magnetic susceptibility, FT-IR, UV-Visible spectroscopy. The Schiff bases in every case behaved as bidentate, uninegative ligands. The complexes of Cu(II), Co(II) and Fe(III) are paramagnetic while all other complexes are diamagnetic. The complexes [Cu(C 11 H 11 N 2 S 2 ) 2 ] and [Ni(C 11 H 11 N 2 S 2 ) 2 ] had, square planar structures with two ligands satisfying the four steriochemical sites, where the complexes [Zn(C 11 H 11 N 2 S 2 ) 2 ] and [Cd(C 11 H 11 N 2 S 2 ) 2 ] were tetrahedral and the complexes [Sn(C 11 H 11 N 2 S 2 ) 2 (H 2 O) 2 ], [Co(C 11 H 11 N 2 S 2 ) 2 (H 2 O) 2 ], [Sb(C 11 H 11 N 2 S 2 ) 2 (NO 3 )(H 2 O)] and [Fe(C 11 H 11 N 2 S 2 ) 2 (NO 3 ) (H 2 O)] were octahedral in geometry. The metal complexes have been screened for their antibacterial activity.

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

Sultana Khan. 2013. "Synthesis, Characterization and Biological Activities of Cu(II), Ni(II), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) Complexes with Schiff base Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate". Global Journal of Science Frontier Research, Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 13 (GJSFR Volume 13 Issue B6).

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords
antimicrobialIR spectrametal complexesUV -Vis Spectra
Classification
GJSFR-B Classification FOR Code: 270000
  • Submission ReceivedJuly 19, 2013
  • Peer Review Double Blind
    Handling Editor
  • Accepted August 10, 2013
  • Published August 20, 2013
Version of record

v1.2

Issue date
September 21, 2013

Language
English
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Synthesis, Characterization and Biological Activities of Cu(II), Ni(II), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) Complexes with Schiff base Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate

Sultana Khan
Sultana Khan Pabna University of Science and Technology
  • Submission ReceivedJuly 19, 2013
  • Peer Review Double Blind
    Handling Editor
  • Accepted August 10, 2013
  • Published August 20, 2013