Synthesis, Characterization, Antibacterial, and Extraction Studies of Dioxouranium (Uo22+)Ofn,N-[(4,4-Biphenyl Bis(Methylidene))]Di Nicotinic Hydrazine

Synthesis, Characterization, Antibacterial, and Extraction Studies of Dioxouranium (Uo22+)Ofn,N-[(4,4-Biphenyl Bis(Methylidene))]Di Nicotinic Hydrazine

Hamid Hussein Eissa

Contact

Hajjah University

Synthesis, Characterization, Antibacterial, and Extraction Studies of Dioxouranium (Uo22+)Ofn,N-[(4,4-Biphenyl Bis(Methylidene))]Di Nicotinic Hydrazine

Article Fingerprint

ReserarchID

AAB9X

AI TAKEAWAY

Connecting with the Eternal Ground

Abstract

New Hydrazonic Schiff base was synthesized by reaction Nicotinic hydrazidewith Biphenyl-4,4′- Dicarbal-dehydehave been characterized by elemental analyses IR, massand1H-NMR spectral data Hydrazoic Schiff base have been studied by liquid-liquid extraction towards the metal ion Uo(II) from aqueous phase to organic phase. behave as a good extractant ligand for uranyl ions Uo(II) from aqueous solution, and the study of conditions of extraction shows that the optimum pH values for extraction was (pH= 5.2), so the suitable concentration of Uo(II) ions in aqueous solution which is giving highest distribution ratio (D) was (1×10-4M), in addition the optimum shaking time to reach the equilibria was (60 min.), as well as the stoichiometric study by using three methods shows the structure of Uo(II) ions complex with ligand was 1 : 1 (metal : ligand), in addition the study of organic solvent effect appear there is no straight line relation between the distribution ratio for extraction of Uo(II) ions and dielectric constant for organic solvents but this study demonstrate there is an effect for the structure of organic solvent used, thermodynamic study shows the complexation reaction an endothermic.The new Schiff Bases was studied for antibacterial activities against (Bacillus subtilis and Staphylococcus aureus) are Gram positive and (Salmonella typhi and Escherichia coli) are Gram negative. The compound ligand was exhibited a variable activity of inhibition on the growth of the bacteria.

References

39 Cites in Article

Reference Format

R Layer (1963). Unknown Title.
Jean-Luc Renaud,Christian Bruneau,Bernard Demerseman (2003). Ruthenium-Bisimine: A New Catalytic Precursor for Regioselective Allylic Alkylation.
Waldo Correa,Stavroula Papadopoulos,Peta Radnidge,Brett Roberts,Janet Scott (2002). Direct, efficient, solvent-free synthesis of 2-aryl-1,2,3,4-tetrahydroquinazolines.
C Johnson,J Atwood,J Steed,C Bauer,R Rogers (1996). Unknown Title.
M Sprung (1940). Unknown Title.
Hossein Naeimi,Javad Safari,Arash Heidarnezhad (2007). Synthesis of Schiff base ligands derived from condensation of salicylaldehyde derivatives and synthetic diamine.
R Ambroziak,E Pelech,T Milchert,Z Dziembowska,J Rozwadowski,A Molcatal,Chem (2004). Unknown Title.
Suga,T Fudo,Ibata (1998). Unknown Title.
Zhuo-Hong Yang,Li-Xin Wang,Zheng-Hong Zhou,Qi-Lin Zhou,Chu-Chi Tang (2001). Synthesis of new chiral Schiff bases and their application in the asymmetric trimethylsilylcyanation of aromatic aldehydes.
K Tony,L Yong (2001). Unknown Title.
Geon‐joong Kim,Ji‐hoon Shin (1999). Application of new unsymmetrical chiral Mn(III), Co(II,III) and Ti(IV) salen complexes in enantioselective catalytic reactions.
K Sasaki,M Nakajima,Kojima (1991). Unknown Title.
Luigi Casella,James Ibers (1981). Synthesis, characterization, and reactivity of copper(I) and copper(II) complexes of N,N'-bis(3-(2-thenylideneimino)propyl)piperazine (tipp) and N,N'-bis(3-(2-thenylamino)propyl)piperazine (tapp). Crystal structure of [Cu(tapp)][ClO4]2.
F Al Zoubi,C Kandil,Khaled (2011). Unknown Title.
R Waldemar,Rainer (1998). Unknown Title.
Jens Schmeyers,Fumio Toda,Juergen Boy,Gerd Kaupp (1998). Quantitative solid–solid synthesis of azomethines.
Tanaka (2003). Solvent-Free Organic Synthesis By K. Tanaka. Wiley−VCH: Weinheim. 2003. 433 pp. £80. ISBN 3-527-30612-9..
Sans,R Perona,J Claramunt,Elquero (2005). Unknown Title.
J Fernández-G,F Del Rio-Portilla,B Quiroz-Garcı́a,R Toscano,R Salcedo (2001). The structures of some ortho-hydroxy Schiff base ligands.
Joseph Sclafani,Maria Maranto,Thomas Sisk,Scott Van Arman (1996). Terminal Alkylation of Linear Polyamines.
J Corhnelissen,J Van Diemen,L Groeneveld,J Haasnoot,A Spek (1992). Unknown Title.
D Richardson,Paul Bernhardt (1999). Crystal and molecular structure of 2-hydroxy-1-naphthaldehyde isonicotinoyl hydrazone (NIH) and its iron(III) complex: an iron chelator with anti-tumour activity.
Mallikarjun Yadawe,Sangamesh Patil (1997). Synthesis, characterization and biological studies of cobalt(II) and nickel(II) complexes with new Schiff bases.
G Darnell,D Richardson (1997). The Potential of Iron Chelators of the Pyridoxal Isonicotinoyl Hydrazone Class as Effective Antiproliferative Agents III: The Effect of the Ligands on Molecular Targets Involved in Proliferation.
Balakrishnan Murukan,Kochukittan Mohanan (2007). Synthesis, characterization and antibacterial properties of some trivalent metal complexes with [(2-hydroxy-1-naphthaldehyde)-3-isatin]-bishydrazone.
J Cmunier-Lamy,Berthelin (2006). World Congress of Soil Science.
Dighton,Tugay,V Nzhdanova,Nzheltonozhsky (2006). 18th World Congress of Soil Science.
Anthony Vaughn,Daniel Bassil,Charles Barnes,Sheryl Tucker,Paul Duval (2006). Contrasting Solvent and Capping Ligand Effects Directing the Photochemistry of Uranyl(VI) Schiff Base Complexes.
Frankuchen (1935). Unknown Title.
Fan Yuhua,Bi Caifeng,Li Jinying (2002). Synthesis and characterization of UO2(II) and Th(IV) binuclear complexes with o-vanillylidene anthranilic acid.
Laura Gagliardi,Ingmar Grenthe,Björn Roos (2001). A Theoretical Study of the Structure of Tricarbonatodioxouranate.
W Oldham,S Oldham,B Scott,S Abnez,W Smith,D Costa (2001). Unknown Title.
Ahmed El-Hendawy,Abd El-Ghany El-Kourashy,Mai Shanab (1992). Schiff base complexes of ruthenium(III), molybdenum(VI) and uranium(VI), and use of the former as catalytic organic oxidants.
M Maurya,R Maurya (1995). Unknown Title.
M Tarafder,A Khan (1991). Unknown Title.
Lionel Salmon,Pierre Thuéry,Michel Ephritikhine (2003). Crystal structure of hetero(bi- and tetra-)metallic complexes of compartmental Schiff bases uniting uranyl and transition metal (Ni2+, Cu2+) ions.
Bülent,C Fatma,Mustafa (2009). Unknown Title.
U Ibrahim,I Basaran,T Kilic,J Cakir (2006). Unknown Title.
A Arifien,A Amerallah,R Awadullah,S Sirro Unknown Title.

Download References

Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

Hamid Hussein Eissa. 2014. \u201cSynthesis, Characterization, Antibacterial, and Extraction Studies of Dioxouranium (Uo22+)Ofn,N-[(4,4-Biphenyl Bis(Methylidene))]Di Nicotinic Hydrazine\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 14 (GJSFR Volume 14 Issue B2).

More Citation Formats

Select Citation Style:

Download Citation

GJSFR Volume 14 Issue B2

Explore Journals Explore Volume Read This Issue

Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords

liquid-liquid extraction nicotinic hydrazide stoichiometric Thermodynamic uranyl ions

Submission ReceivedApril 30, 2014
Peer Review Double Blind
Handling Editor
Accepted May 27, 2014
Published June 9, 2014

Version of record

v1.2

Issue date

May 28, 2014

Language

Experiance in AR

Explore published articles in an immersive Augmented Reality environment. Our platform converts research papers into interactive 3D books, allowing readers to view and interact with content using AR and VR compatible devices.

View in VR

Read in 3D

Your published article is automatically converted into a realistic 3D book. Flip through pages and read research papers in a more engaging and interactive format.

View in 3D

Article Matrices

Total Score: 101

Country: Yemen

Subject: Global Journal of Science Frontier Research - B: Chemistry

Authors: Hamid Hussein Eissa (PhD/Dr. count: 0)

View Count (all-time): 171

Total Views (Real + Logic): 4763

Total Downloads (simulated): 2444

Publish Date: 2014 05, Wed

Monthly Totals (Real + Logic):

Month 1: 36 views
Month 2: 51 views
Month 3: 45 views
Month 4: 35 views
Month 5: 47 views
Month 6: 52 views
Month 7: 28 views
Month 8: 44 views
Month 9: 29 views
Month 10: 35 views
Month 11: 45 views
Month 12: 32 views
Month 13: 30 views
Month 14: 21 views
Month 15: 38 views
Month 16: 29 views
Month 17: 29 views
Month 18: 26 views
Month 19: 40 views
Month 20: 38 views
Month 21: 33 views
Month 22: 28 views
Month 23: 15 views
Month 24: 43 views
Month 25: 29 views
Month 26: 24 views
Month 27: 41 views
Month 28: 42 views
Month 29: 49 views
Month 30: 28 views
Month 31: 32 views
Month 32: 47 views
Month 33: 26 views
Month 34: 27 views
Month 35: 26 views
Month 36: 24 views
Month 37: 21 views
Month 38: 32 views
Month 39: 45 views
Month 40: 35 views
Month 41: 34 views
Month 42: 37 views
Month 43: 26 views
Month 44: 38 views
Month 45: 41 views
Month 46: 26 views
Month 47: 30 views
Month 48: 26 views
Month 49: 21 views
Month 50: 31 views
Month 51: 23 views
Month 52: 20 views
Month 53: 42 views
Month 54: 12 views
Month 55: 21 views
Month 56: 28 views
Month 57: 33 views
Month 58: 25 views
Month 59: 24 views
Month 60: 35 views
Month 61: 25 views
Month 62: 33 views
Month 63: 36 views
Month 64: 37 views
Month 65: 22 views
Month 66: 35 views
Month 67: 36 views
Month 68: 33 views
Month 69: 35 views
Month 70: 18 views
Month 71: 36 views
Month 72: 12 views
Month 73: 11 views
Month 74: 21 views
Month 75: 36 views
Month 76: 34 views
Month 77: 25 views
Month 78: 30 views
Month 79: 28 views
Month 80: 30 views
Month 81: 22 views
Month 82: 25 views
Month 83: 36 views
Month 84: 34 views
Month 85: 27 views
Month 86: 37 views
Month 87: 37 views
Month 88: 27 views
Month 89: 45 views
Month 90: 23 views
Month 91: 18 views
Month 92: 27 views
Month 93: 40 views
Month 94: 20 views
Month 95: 36 views
Month 96: 33 views
Month 97: 30 views
Month 98: 30 views
Month 99: 18 views
Month 100: 16 views
Month 101: 40 views
Month 102: 22 views
Month 103: 39 views
Month 104: 33 views
Month 105: 36 views
Month 106: 37 views
Month 107: 30 views
Month 108: 32 views
Month 109: 44 views
Month 110: 18 views
Month 111: 37 views
Month 112: 40 views
Month 113: 21 views
Month 114: 40 views
Month 115: 32 views
Month 116: 38 views
Month 117: 25 views
Month 118: 33 views
Month 119: 38 views
Month 120: 21 views
Month 121: 42 views
Month 122: 29 views
Month 123: 20 views
Month 124: 30 views
Month 125: 40 views
Month 126: 27 views
Month 127: 35 views
Month 128: 44 views
Month 129: 50 views
Month 130: 19 views
Month 131: 38 views
Month 132: 44 views
Month 133: 25 views
Month 134: 37 views
Month 135: 45 views
Month 136: 48 views
Month 137: 25 views
Month 138: 44 views
Month 139: 53 views
Month 140: 31 views
Month 141: 16 views
Month 142: 54 views
Month 143: 51 views
Month 144: 47 views

Total Views: 4763

Total Downloads: 2444

2026 Trends

Our website is actively being updated, and changes may occur frequently. Please clear your browser cache if needed. For feedback or error reporting, please email [email protected]