Synthesisof Zirconium Containing Mesoporous Material for the Efficient Catalytic Esterification of Benzyl Alcohol and Acetic Acid

Thualfeqar G Mohammed

Synthesisof Zirconium Containing Mesoporous Material for the Efficient Catalytic Esterification of Benzyl Alcohol and Acetic Acid

Dr. Thualfeqar G Mohammed * § PhD Candidate at Mississippi State University

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§ Universiti Teknologi Malaysia & University of Kufa

Synthesisof Zirconium Containing Mesoporous Material for the Efficient Catalytic Esterification of Benzyl Alcohol and Acetic Acid

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Abstract

This research focuses on the synthesis of metal-containin gmesoporous silica for catalytic esterification of benzyl alcohol with acetic acid. In this study Zr-containing MCM-41 with different molar ratios of Si/Zr were synthesized successfully. It is observed that the structural ordering of Zr-MCM-41varies with the Si/Zr ratio, and highly ordered mesoporous molecular sieves could be obtained for a Si/Zr molar ratio larger than 5. Calcination may significantly improve the structural regularity. In esterification reaction of benzyl alcohol with acetic acid, the benzyl alcohol conversion over all the Zr-MCM-41catalysts linearly increases with increasing the reaction temperature and selectivity to benzyl acetate was 100 %. The molar ratios of reactants also were investigated for final product yield; the molar ratio of acetic acid to benzyl alcohol can be 2:1 for high yield.

References

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

Dr. Thualfeqar G Mohammed. 2016. "Synthesisof Zirconium Containing Mesoporous Material for the Efficient Catalytic Esterification of Benzyl Alcohol and Acetic Acid". Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 16 (GJSFR Volume 16 Issue 25 (B3)).

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GJSFR Volume 16 Issue 25 (B3)

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords

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Classification

GJSFR-B Classification FOR Code: 250399p

Submission ReceivedAugust 24, 2016
Peer Review Double Blind
Handling Editor
Accepted September 16, 2016
Published August 19, 2016

Version of record

v1.2

Issue date

August 19, 2016

Language

English

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Article Matrices

Total Score: 102

Country: Iraq

Subject: Global Journal of Science Frontier Research - B: Chemistry

Authors: Mehdi Erfani Jazi, Thualfeqar G Mohammed (PhD/Dr. count: 0)

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Publish Date: 2016 08, Fri

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