Transformations of Vegetables Oils in Supercritical Methyl and Ethyl Acetates in Continuous Flow Reactor

Transformations of Vegetables Oils in Supercritical Methyl and Ethyl Acetates in Continuous Flow Reactor

V. I. Anikeev

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V. P. Sivcev

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E. YU. Yakovleva

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α Boreskov Institute of Catalysis

Transformations of Vegetables Oils in Supercritical Methyl and Ethyl Acetates in Continuous Flow Reactor

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Abstract

The transesterification reactions of sunflower and corn oils in supercritical methyl and ethyl acetates in a tubular flow reactor without catalyst were studied. The residence time of the reaction mixture was ~2.9 min. The reaction of sunflower oil in supercritical methyl acetate yielded a large amount of free fatty acids and respective esters. The fraction of free fatty acids among the reaction products at high temperatures attained 50%. The product distributions in the transesterification reactions of vegetable oils with supercritical methyl and ethyl acetates were studied in detail. The methods of qualitative and quantitative analysis of the reaction products have been developed.

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Reference Format

D Kusdiana,S Saka (2001). Kinetics of transesterification in rapeseed oil to biodiesel fuels as treated in supercritical methanol.
Dadan Kusdiana,Shiro Saka (2004). Effects of water on biodiesel fuel production by supercritical methanol treatment.
S Saka,D Kusdiana (2001). Biodiesel fuel from rapeseed prepared in supercritical methanol.
Ayhan Demirbas (2007). Biodiesel from sunflower oil in supercritical methanol with calcium oxide.
Kok Tat Tan,Teong Keat,Lee (2011). A review on supercritical fluids (SCF) technology in sustainable biodiesel production: Potential and challenges.
Warintorn Thitsartarn,Sibudjing Kawi (2011). Transesterification of oil by sulfated Zr-supported mesoporous silica.
Surbhi Semwal,Ajay Arora,Rajendra Badoni,Deepak Tuli (2011). Biodiesel production using heterogeneous catalysts.
J Melero,R Van Grieken,G Morales,M Paniagua (2007). Acid mesoporous silica for the acetylation of glycerol: synthesis of bioadditives to petrol fuel.
Edgar Lotero,Yijun Liu,Dora Lopez,Kaewta Suwannakarn,David Bruce,James Goodwin (2005). Synthesis of Biodiesel via Acid Catalysis.
J Zhang,S Chen,R Yang,Y Yan (2010). Biodiesel production from vegetable oil usisng heterogenous acid and alkali catalyst.
Y Sharma,B Singh,J Korstad (2011). Latest developments on application of heterogenous basic catalysts for an efficient and eco friendly synthesis of biodiesel: A review.
Peng Xie Wenlei,Chen Hong,Ligong (2006). Transesterification of soybean oil catalyzed by potassium loaded on alumina as a solid-base catalyst.
Maria-Isabel Galan,Jordi Bonet,Romain Sire,Jean-Michel Reneaume,Alexandra Pleşu (2009). From residual to useful oil: Revalorization of glycerine from the biodiesel synthesis.
Hanifa Taher,Sulaiman Al-Zuhair,Ali Al-Marzouqi,Yousef Haik,Mohammed Farid (2011). A Review of Enzymatic Transesterification of Microalgal Oil-Based Biodiesel Using Supercritical Technology.
Luiz Franken,Naiane Marcon,Helen Treichel,Débora Oliveira,Denise Freire,Cláudio Dariva,Jaqueline Destain,J Oliveira (2010). Effect of Treatment with Compressed Propane on Lipases Hydrolytic Activity.
N Os´orio,M Ribeiro,M Da Fonseca,S Ferreira-Dias (2008). Interesterification of fat blends rich in -3 polyunsaturated fatty acids catalysed by immobilized Thermomyces lanuginosa lipase under high pressure.
Pasquale Campanelli,Mauro Banchero,Luigi Manna (2010). Synthesis of biodiesel from edible, nonedible and waste cooking oils via supercritical methyl acetate transesterification.
Shiro Saka,Yohei Isayama (2009). A new process for catalyst-free production of biodiesel using supercritical methyl acetate.
Kok Tan,Keat Lee,Abdul Mohamed (2010). A glycerol-free process to produce biodiesel by supercritical methyl acetate technology: An optimization study via Response Surface Methodology.
Cholada Komintarachat,Ruengwit Sawangkeaw,Somkiat Ngamprasertsith (2015). Continuous production of palm biofuel under supercritical ethyl acetate.
K Harvind,Tapaswy Reddy,Muppaneni,D Prafulla,Sundaravadivelnathan Patil,Peter Ponnusamy,Tanner Cooke,Shuguang Schaub,Deng (2014). Direct conversion of wet algae to crude biodiesel under supercritical ethanol conditions.
M Niza,K Tan,K Lee,Z Ahmad (2013). Influence of impurities on biodiesel production from Jatropha curcas L. by supercritical methyl acetate process.
V Anikeev,E Yakovleva (2012). Transesterification of rapeseed oil in supercritical methanol in a flow reactor.
V Anikeev,E Yakovleva (2013). Biodiesel synthesis from vegetable oils with supercritical methanol.
Vladimir Anikeev (2014). Synthesis of Biodiesel Fuel in Supercritical Lower Alcohols with and without Heterogeneous Catalysts (Thermodynamics, Phase and Chemical Equilibriums, Experimental Studies).

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

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Not applicable for this article.

How to Cite This Article

V. I. Anikeev. 2016. \u201cTransformations of Vegetables Oils in Supercritical Methyl and Ethyl Acetates in Continuous Flow Reactor\u201d. Global Journal of Research in Engineering - C: Chemical Engineering GJRE-C Volume 16 (GJRE Volume 16 Issue C1): .

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GJRE Volume 16 Issue C1
Pg. 21- 27

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Journal Specifications

Crossref Journal DOI 10.17406/gjre

Print ISSN 0975-5861

e-ISSN 2249-4596

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GJRE-C Classification: FOR Code: 090499

Submission ReceivedDecember 16, 2015
Peer Review Double Blind
Handling Editor
Accepted December 31, 2015
Published January 15, 2016

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v1.2

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August 3, 2016

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Total Score: 103

Country: Unknown

Subject: Global Journal of Research in Engineering - C: Chemical Engineering

Authors: V. I. Anikeev, V. P. Sivcev, E. YU. Yakovleva (PhD/Dr. count: 0)

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Publish Date: 2016 08, Wed

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