Triarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions

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Ram Nath Prasad Yadav
Ram Nath Prasad Yadav
1 Tribhuvan University

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A series of new triarylantimony(V) dicarboxylates of the general formula Ar 3 SbL 2 (where Ar = C 6 H 5 and L = C 6 H 5 CONHCH 2 COO -, C 6 H 2 (OH) 3 COO -, C 6 H 5 COO -, C 6 H 5 C 2 H 2 COO -, C 6 H 4 (OH)COO -, (C 6 H 5 ) 2 (OH)C.COO -) have been prepared by the reaction of triarylantimony(V) dichloride and a carboxylic acid in the presence of triethylamine as well as the metathesis of sodium or silver salt of the carboxylic acid andtriarylantimony(V) dichloride. The newly synthesized compounds have been characterized by conventional methods. A tentative trigonalbipyramidal structure is suggested in which (OCOR) group occupy axial position and the three organic groups are situated at the equatorial position. The melting points of compounds did not change even after prolong stirring with water at room temperature for several hours indicating their hydrolytic stability.

Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

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No ethics committee approval was required for this article type.

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Not applicable for this article.

Ram Nath Prasad Yadav. 2015. \u201cTriarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 15 (GJSFR Volume 15 Issue B3): .

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GJSFR Volume 15 Issue B3
Pg. 35- 39
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Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

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GJSFR-B Classification: FOR Code: 259999
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v1.2

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June 11, 2015

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English

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A series of new triarylantimony(V) dicarboxylates of the general formula Ar 3 SbL 2 (where Ar = C 6 H 5 and L = C 6 H 5 CONHCH 2 COO -, C 6 H 2 (OH) 3 COO -, C 6 H 5 COO -, C 6 H 5 C 2 H 2 COO -, C 6 H 4 (OH)COO -, (C 6 H 5 ) 2 (OH)C.COO -) have been prepared by the reaction of triarylantimony(V) dichloride and a carboxylic acid in the presence of triethylamine as well as the metathesis of sodium or silver salt of the carboxylic acid andtriarylantimony(V) dichloride. The newly synthesized compounds have been characterized by conventional methods. A tentative trigonalbipyramidal structure is suggested in which (OCOR) group occupy axial position and the three organic groups are situated at the equatorial position. The melting points of compounds did not change even after prolong stirring with water at room temperature for several hours indicating their hydrolytic stability.

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Triarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions

Ram Nath Prasad Yadav
Ram Nath Prasad Yadav Tribhuvan University

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