Triarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions

Ram Nath Prasad Yadav

Triarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions

Ram Nath Prasad Yadav * §

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Tribhuvan University

Triarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions

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Abstract

A series of new triarylantimony(V) dicarboxylates of the general formula Ar 3 SbL 2 (where Ar = C 6 H 5 and L = C 6 H 5 CONHCH 2 COO -, C 6 H 2 (OH) 3 COO -, C 6 H 5 COO -, C 6 H 5 C 2 H 2 COO -, C 6 H 4 (OH)COO -, (C 6 H 5 ) 2 (OH)C.COO -) have been prepared by the reaction of triarylantimony(V) dichloride and a carboxylic acid in the presence of triethylamine as well as the metathesis of sodium or silver salt of the carboxylic acid andtriarylantimony(V) dichloride. The newly synthesized compounds have been characterized by conventional methods. A tentative trigonalbipyramidal structure is suggested in which (OCOR) group occupy axial position and the three organic groups are situated at the equatorial position. The melting points of compounds did not change even after prolong stirring with water at room temperature for several hours indicating their hydrolytic stability.

References

17 Cites in Article

Reference Format

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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

Ram Yadav. 2015. "Triarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions". Global Journal of Science Frontier Research, Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 15 (GJSFR Volume 15 Issue B3).

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GJSFR Volume 15 Issue B3

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Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords

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Classification

GJSFR-B Classification FOR Code: 259999

Submission ReceivedApril 29, 2015
Peer Review Double Blind
Handling Editor
Accepted May 25, 2015
Published June 5, 2015

Version of record

v1.2

Issue date

June 11, 2015

Language

English

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Article Matrices

Total Score: 145

Country: Nepal

Subject: Global Journal of Science Frontier Research

Authors: Ram Nath Prasad Yadav (PhD/Dr. count: 0)

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