Research
Preparation of Capsules containing L-Cysteine with Melting Dispersion Cooling Method
It was tried to prepare the capsules containing L-cysteine with the melting dispersion cooling method. Tripalmitin was selected as the shell material in order to keep out water and a few fatty acid esters such as ethyl laurate, ethyl stearate, ethyl myristate, ethyl oleate, ethyl palmitate and bees wax were added in the shell material as the modification materials in order to improve the water proof of the capsule shell. Furthermore, the capsules were coated by the coating materials such as oleic acid, ethyl oleate, triolein and ethyl laurate. It was investigated how the concentration of oil soluble surfactant and the combination of the shell material with both the modification materials and the coating materials affected the characteristics of capsules such as the content and the release feature of core material, the water proof and the swelling degree of capsules. With increasing the concentration of oil soluble surfactant, the released ratio decreased, become minimum and then, increased. The content could be increased by addition of modification materials. It was found that the released ratio was considerably depressed by ethyl laurate and ethyl palmitate as the modification materials and by oleic acid as the coating material and promoted by bees wax as the modification materials.
Preparation of Microcapsules Containing Grape Polyphenols and I-Tocopherol by Spray-Gelling Method
It was tried to prepare the microcapsules containing the (W/O) emulsion or the (S/O) dispersion by the Spray-Gelling method. The shell material was gelled sodium alginate. In the case of preparation of the microcapsules containing the (W/O) emulsion, grape polyphenol as the first core was dissolved in the inner water droplets which were dispersed in α-tocopherol oil as the second core. In the case of preparation of the microcapsules containing the (S/O) dispersion, grape polyphenol powder as the first core was dispersed in the α-tocopherol oil as the second core. Two kinds of multiple emulsions such as the (W/O)/W emulsion and the (S/O)/W emulsion, in which the sodium alginate aqueous solution was the continuous water phase, were prepared and sprayed into the calcium chloride aqueous solution as the gelling agent through the nozzle. The microcapsules with the mean diameters from 20 to 70 μm could be prepared. The microencapsulation efficiency was increased by changing the (W/O) emulsion to the (S/O) dispersion.
