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A combined mechanism of nonequilibrium dislocation growth of crystal faces combined with equilibrium formation of a two-dimensional nucleation is presented. The binding energy of atoms in the crystal near the helical dislocation has been calculated based on the Lennard-Jones potential. The study substantiates thermodynamic conditions for the occurrence of hollow dislocation nuclei detected earlier in AFM observations of crystal growth. Conditions for the linear Onsager approximation in response to non-linear kinetics of crystal growth are described. The three values of solution supersaturation, the relationships between which are highly variable, are controlling the growth process of the crystal face. The supersaturation and their interrelations depend on the peculiarities of the defective crystal structure, the of the crystal-solution interaction, and the peculiarities of the crystallization medium hydrodynamics.
V.I. Rakin. 2026. \u201cTwo-Dimensional Nucleation in the Dislocation Model of Crystal Growth\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 23 (GJSFR Volume 23 Issue B1): .
Crossref Journal DOI 10.17406/GJSFR
Print ISSN 0975-5896
e-ISSN 2249-4626
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Total Score: 101
Country: Ukraine
Subject: Global Journal of Science Frontier Research - B: Chemistry
Authors: V.I. Rakin (PhD/Dr. count: 0)
View Count (all-time): 145
Total Views (Real + Logic): 1390
Total Downloads (simulated): 53
Publish Date: 2026 01, Fri
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A combined mechanism of nonequilibrium dislocation growth of crystal faces combined with equilibrium formation of a two-dimensional nucleation is presented. The binding energy of atoms in the crystal near the helical dislocation has been calculated based on the Lennard-Jones potential. The study substantiates thermodynamic conditions for the occurrence of hollow dislocation nuclei detected earlier in AFM observations of crystal growth. Conditions for the linear Onsager approximation in response to non-linear kinetics of crystal growth are described. The three values of solution supersaturation, the relationships between which are highly variable, are controlling the growth process of the crystal face. The supersaturation and their interrelations depend on the peculiarities of the defective crystal structure, the of the crystal-solution interaction, and the peculiarities of the crystallization medium hydrodynamics.
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