Two-Dimensional Nucleation in the Dislocation Model of Crystal Growth

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V.I. Rakin
V.I. Rakin

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Two-Dimensional Nucleation in the Dislocation Model of Crystal Growth

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Abstract

A combined mechanism of nonequilibrium dislocation growth of crystal faces combined with equilibrium formation of a two-dimensional nucleation is presented. The binding energy of atoms in the crystal near the helical dislocation has been calculated based on the Lennard-Jones potential. The study substantiates thermodynamic conditions for the occurrence of hollow dislocation nuclei detected earlier in AFM observations of crystal growth. Conditions for the linear Onsager approximation in response to non-linear kinetics of crystal growth are described. The three values of solution supersaturation, the relationships between which are highly variable, are controlling the growth process of the crystal face. The supersaturation and their interrelations depend on the peculiarities of the defective crystal structure, the of the crystal-solution interaction, and the peculiarities of the crystallization medium hydrodynamics.

References

18 Cites in Article
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Funding

No external funding was declared for this work.

Conflict of Interest

The authors declare no conflict of interest.

Ethical Approval

No ethics committee approval was required for this article type.

Data Availability

Not applicable for this article.

How to Cite This Article

V.I. Rakin. 2026. \u201cTwo-Dimensional Nucleation in the Dislocation Model of Crystal Growth\u201d. Global Journal of Science Frontier Research - B: Chemistry GJSFR-B Volume 23 (GJSFR Volume 23 Issue B1): .

Download Citation

Nucleation, crystal growth, microstructure, dislocation, crystal formation, materials science, physics, solid state.
Issue Cover
GJSFR Volume 23 Issue B1
Pg. 21- 29
Journal Specifications

Crossref Journal DOI 10.17406/GJSFR

Print ISSN 0975-5896

e-ISSN 2249-4626

Keywords
Classification
GJSFR-B Classification: FOR Code: 020304
Version of record

v1.2

Issue date

February 21, 2023

Language
en
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Published Article

A combined mechanism of nonequilibrium dislocation growth of crystal faces combined with equilibrium formation of a two-dimensional nucleation is presented. The binding energy of atoms in the crystal near the helical dislocation has been calculated based on the Lennard-Jones potential. The study substantiates thermodynamic conditions for the occurrence of hollow dislocation nuclei detected earlier in AFM observations of crystal growth. Conditions for the linear Onsager approximation in response to non-linear kinetics of crystal growth are described. The three values of solution supersaturation, the relationships between which are highly variable, are controlling the growth process of the crystal face. The supersaturation and their interrelations depend on the peculiarities of the defective crystal structure, the of the crystal-solution interaction, and the peculiarities of the crystallization medium hydrodynamics.

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Two-Dimensional Nucleation in the Dislocation Model of Crystal Growth

V.I. Rakin
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