A series of new stable adducts of tris (pentafluo-rophenyl)antimony(V) diisothiocyante of the type (C6H5)3 Sb(NCS)2.L. Where, L = dipropyl formamide (DPF), 3-methylpyridine(3-Picoline), dimethyl formamide (DMF), tryphenylphosphine oxide(Ph3PO), triphenylarsine oxide (Ph3AsO), dimethyl sulfoxide (DMSO), thiourea (TU), pyridine(C5H5N) have been synthesized by the reaction of tris (pentaflu...