An efficient method has been developed for the preparation of three novel heterocyclic compounds: Bridgehead-fused-5-methyl-6-methylketone-1,2,3-triazolo[5,1-c]-1,2,4-triazine(12), Bridgehead-fused-5-methoxyl -6- methylester-1,2,3-triazolo-[5,1-c]-1,2,4-triazine (14) and Bridgehead - fused - 5-methyl- 6-methylester-1,2,3-triazolo-[5,1-c] -1,2,4-triazine (16). The new heterocyclic systems...