Dielectric properties of order-disorder type crystals

Dr. V. S. Bist , N. S. Panwar

Volume 12 Issue 7

Global Journal of Science Frontier Researc

The soft mode dynamical model has been used to study the dielectric properties of order-disorder-type crystals. Using the model Hamiltonian proposed by Blinc [Advances in Phys, 29 (1972) 701] and has been modified by Bist et al [GJSFR,10,18(2010)], the expressions for the dielectric constant and tangent loss have been derived and discussed for order-disorder, KH2PO4 type-crystals with the help of double time temperature dependent Green’s function techniques and Dyson’s equation treatment. Using appropriate parameters given by Ganguli et al [Phys Rev. B21, 2937 (1980)] the transverse dielectric constant and observed dielectric constant have been calculated and compared with experimental results of Raman Intensity[Ferroelectrics 52, 91 (1983)], Busch [Helv. Phys. Acta. 11, 265 (1938)], Kaminow et al [Phys. Rev. 138A, 1539 (1963)], and Deguchi et al [J. Phys. Soc. Jpn. 49, 1887 (1980)]. The observed dielectric constant explains the Curie-Weiss behaviour of dielectric constant along the c-axis of KH2PO4 crystal in the paraelectric phase. Also the temperature dependence of tangent loss in paraelectric phase for KH2PO4 at 9.2 GHz for field along the a-axis, and the c-axis have been calculated and compared with experimental results of Kaminow et al [Phys. Rev. 138A, 1539 (1963)]. It is observed that these results are in good agreement with each other and with the results obtained by other methods. At higher temperature the loss deviates from the Curie-Weiss type behaviour and increases linearly with temperature. This behaviour suggests that at higher temperatures the phonon anharmonicity contributes significantly in the observed loss.